Synthesis of thermally stable SBT and SBS/SBT intergrowth zeolites

Science ◽  
2021 ◽  
Vol 373 (6550) ◽  
pp. 104-107 ◽  
Author(s):  
Hwajun Lee ◽  
Jiho Shin ◽  
Kyounghwan Lee ◽  
Hyun June Choi ◽  
Alvaro Mayoral ◽  
...  
Keyword(s):  
Molecular Sieves ◽  
Thermal Instability ◽  
Zeolite Y ◽  
Three Dimensional ◽  
Thermally Stable ◽  
Synergy Effect ◽  
Organic Structure ◽  
Catalytic Application ◽  
Inorganic Cation ◽  
Channel Systems

UCSB-6 (framework type SBS) and UCSB-10 (SBT), two three-dimensional phosphate-based molecular sieves with supercages accessible through 12-ring (circumscribed by 12 tetrahedral atoms) windows, are structurally similar to the hexagonal and cubic polytypes of faujasite or zeolite Y, an industrially relevant catalyst, but the cage structures are substantially different. Nonetheless, their inherent thermal instability has precluded any catalytic application so far. By using multiple inorganic cation and charge density mismatch approaches, we synthesized PST-32 and PST-2, a thermally stable aluminosilicate version of UCSB-10 and the hypothetical SBS/SBT intergrowth family member, respectively. This study suggests that many hypothetical cage-based zeolite structures with multidimensional channel systems can be synthesized as compositionally robust forms by systematically exploring the synergy effect of inorganic and organic structure–directing agents.

Mesoporosity of Zeolite Y: Quantitative Three-Dimensional Study by Image Analysis of Electron Tomograms

2012 ◽  
Vol 124 (17) ◽  
pp. 4289-4293 ◽  
Author(s):  
Jovana Zečević ◽  
Cedric J. Gommes ◽  
Heiner Friedrich ◽  
Petra E. de Jongh ◽  
Krijn P. de Jong
Keyword(s):  
Image Analysis ◽  
Zeolite Y ◽  
Three Dimensional

scholarly journals catena-Poly[bis(1,3-benzothiazol-3-ium) [[dichloridoantimonate(III)]-di-μ-chlorido-μ-oxido-[chloridoantimonate(III)]-μ-chlorido]]

2016 ◽  
Vol 72 (2) ◽  
pp. 212-214
Author(s):  
Oussama Chebout ◽  
Mhamed Boudraa ◽  
Sofiane Bouacida ◽  
Hocine Merazig ◽  
Chaouki Boudaren
Keyword(s):  
Crystal Packing ◽  
Three Dimensional ◽  
Organic Cations ◽  
Ionic Structure ◽  
Compound C ◽  
Dimensional Network ◽  
Inorganic Cation ◽  
Distorted Octahedral ◽  
Common Face ◽  
Cl Atoms

The title compound, {(C7H6NS)2[Sb2Cl6O]}n, contains two benzothiazolidium cations and one tri-μ-chlorido-trichlorido-μ-oxido-diantimonate(III) anion. The structure of the inorganic cation may be described as as being built up from two polyhedra,i.e.a square-pyramidal SbCl4O and a distorted octahedral SbOCl5unit, sharing a common face (comprising the O atom and two Cl atoms). The two benzothiazole cations are quasi-planar and subtend a dihedral angle of 19.93 (5)°. The crystal packing can be described by alternating (100) layers and [001] chains of the organic cations and inorganic anions connected through an extensive three-dimensional network of N—H...Cl, C—H...O and C—H...Cl hydrogen bonds. This is consolidated by slipped π–π stacking, with centroid-to-centroid distances between the benzothiazole rings of 3.7111 (18)–3.8452 (16) Å. These interactions link the molecules within the layers and also link the layers together and reinforce the cohesion of the ionic structure.

Direct synthesis of three-dimensional MWW zeolite with cyclohexylamine as an organic structure-directing agent

2018 ◽  
Vol 6 (26) ◽  
pp. 12244-12249 ◽  
Author(s):  
Weifeng Chu ◽  
Xiujie Li ◽  
Shenglin Liu ◽  
Xiangxue Zhu ◽  
Sujuan Xie ◽  
...  
Keyword(s):  
Direct Synthesis ◽  
Three Dimensional ◽  
Cost Effective ◽  
Hydrothermal Conditions ◽  
Structure Directing Agent ◽  
Organic Structure ◽  
Low Toxicity ◽  
Mww Zeolite

MCM-49 zeolite with a three-dimensional MWW framework was directly synthesized using low-toxicity and cost-effective cyclohexylamine (CHA) as an organic structure-directing agent under hydrothermal conditions.

A Family of Molecular Sieves Containing Framework-Bound Organic Structure-Directing Agents

2015 ◽  
Vol 127 (38) ◽  
pp. 11249-11253 ◽  
Author(s):  
Jun Kyu Lee ◽  
Jiho Shin ◽  
Nak Ho Ahn ◽  
Alessandro Turrina ◽  
Min Bum Park ◽  
...  
Keyword(s):  
Molecular Sieves ◽  
Organic Structure ◽  
Structure Directing Agents

Synthesis of (Silico)aluminophosphate Molecular Sieves Using an Alkanolamine as a Novel Organic Structure-directing Agent

2015 ◽  
Vol 44 (10) ◽  
pp. 1300-1302
Author(s):  
Xiying Li ◽  
Watcharop Chaikittisilp ◽  
Zhendong Liu ◽  
Yutaka Yanaba ◽  
Takeshi Yoshikawa ◽  
...  
Keyword(s):  
Molecular Sieves ◽  
Structure Directing Agent ◽  
Organic Structure ◽  
Aluminophosphate Molecular Sieves

scholarly journals Functionalized Mesoporous Silica Membranes for CO2Separation Applications

2015 ◽  
Vol 2015 ◽  
pp. 1-9 ◽  
Author(s):  
Hyung-Ju Kim ◽  
Hee-Chul Yang ◽  
Dong-Yong Chung ◽  
In-Hwan Yang ◽  
Yun Jung Choi ◽  
...  
Keyword(s):  
Mesoporous Silica ◽  
Molecular Sieves ◽  
Three Dimensional ◽  
Molecular Transport ◽  
Advanced Materials ◽  
Silica Membranes ◽  
Surface Areas ◽  
Functionalized Mesoporous Silica ◽  
Potential Applications ◽  
And Performance

Mesoporous silica molecular sieves are emerging candidates for a number of potential applications involving adsorption and molecular transport due to their large surface areas, high pore volumes, and tunable pore sizes. Recently, several research groups have investigated the potential of functionalized mesoporous silica molecular sieves as advanced materials in separation devices, such as membranes. In particular, mesoporous silica with a two- or three-dimensional pore structure is one of the most promising types of molecular sieve materials for gas separation membranes. However, several important challenges must first be addressed regarding the successful fabrication of mesoporous silica membranes. First, a novel, high throughput process for the fabrication of continuous and defect-free mesoporous silica membranes is required. Second, functionalization of mesopores on membranes is desirable in order to impart selective properties. Finally, the separation characteristics and performance of functionalized mesoporous silica membranes must be further investigated. Herein, the synthesis, characterization, and applications of mesoporous silica membranes and functionalized mesoporous silica membranes are reviewed with a focus on CO2separation.

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