Elastic properties of D2O ices in solid-state amorphization and transformations between amorphous phases

JETP Letters ◽  
2003 ◽  
Vol 78 (8) ◽  
pp. 488-492 ◽  
Author(s):  
E. L. Gromnitskaya ◽  
O. V. Stal'gorova ◽  
A. G. Lyapin ◽  
V. V. Brazhkin ◽  
O. B. Tarutin
1994 ◽  
Vol 343 ◽  
Author(s):  
Ralf Busch ◽  
Frank Gaertner ◽  
Susanne Schneider ◽  
Rüdiger Bormann ◽  
Peter Haasen

ABSTRACTBased on atom probe field ion microscopy (AP/FIM) studies, electromotive force (EMF) measurements and CALPHAD calculations we discuss the earliest stage of the solid state amorphization reaction (SSAR) in Zr/Co-layers. The AP measurements show that two amorphous phases are formed at the Zr/Co interface from the early stages of the reaction. The metastable two phase field between these amorphous phases is shown by direct measurement of the chemical potential of Zr in amorphous co-sputtered ZrCo alloys by the EMF method. The comparison between the atom probe data and the CALPHAD calculation shows that the interfaces between the different layers are far away from metastable equilibrium in the beginning of the reaction. The amorphous phase formation at the Zr/Co interface and in the hcp-Zr grain boundary is preceded by a supersaturation of the hep ZrCo solid solution that transforms polymorphically into the amorphous state.


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Vol 14 (41) ◽  
pp. 9713-9724 ◽  
Author(s):  
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R J Cooper ◽  
J-M Greneche ◽  
N Cowlam

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