Prediction of the preferable mechanism of nucleophilic substitution at saturated carbon atom and prognosis of S N 1 rate constants by means of QSPR

Rate Constants ◽

Nucleophilic substitution at a saturated carbon atom. VIII. Nonnucleophilicity of inorganic ion pairs

Journal of the American Chemical Society ◽

10.1021/ja01036a065 ◽

1969 ◽

Vol 91 (8) ◽

pp. 2140-2141 ◽

Cited By ~ 2

Author(s):

Richard A. Sneen ◽

F. Robert Rolle

Keyword(s):

Carbon Atom ◽

Ion Pairs ◽

Inorganic Ion ◽

235. Mechanism of substitution at a saturated carbon atom. Part LIII. Conductances of some quaternary ammonium salts in benzene, as a preliminary to the study of unimolecular nucleophilic substitution in that solvent

10.1039/jr9570001206 ◽

1957 ◽

pp. 1206 ◽

Cited By ~ 19

Author(s):

E. D. Hughes ◽

C. K. Ingold ◽

S. Patai ◽

Y. Pocker

Keyword(s):

Carbon Atom ◽

Quaternary Ammonium ◽

Quaternary Ammonium Salts ◽

Ammonium Salts ◽

Nucleophilicity towards a saturated carbon atom: rate constants for the aminolysis of methyl 4-nitrobenzenesulfonate in aqueous solution. A comparison of the n and N + parameters for amine nucleophilicity

Journal of the Chemical Society Perkin Transactions 2 ◽

10.1039/p29940002291 ◽

1994 ◽

pp. 2291 ◽

Cited By ~ 33

Author(s):

John W. Bunting ◽

Jacqueline M. Mason ◽

Christina K. M. Heo

Keyword(s):

Aqueous Solution ◽

Carbon Atom ◽

Rate Constants ◽

255. Solvation of ions. Part II. Dipolar aprotic solvents as media for nucleophilic substitution reactions at a saturated carbon atom

10.1039/jr9610001328 ◽

1961 ◽

pp. 1328 ◽

Cited By ~ 34

Author(s):

A. J. Parker

Keyword(s):

Carbon Atom ◽

Aprotic Solvents ◽

Substitution Reactions ◽

Nucleophilic Substitution Reactions ◽

Solvation Of Ions ◽

Dipolar Aprotic Solvents ◽

Oxidative Substitution of Halogen Atoms in Organic Halogeno-derivatives — a New Type of Nucleophilic Substitution Reactions at a Saturated Carbon Atom

Russian Chemical Reviews ◽

10.1070/rc1988v057n08abeh003388 ◽

1988 ◽

Vol 57 (8) ◽

pp. 760-775 ◽

Cited By ~ 2

Author(s):

L S Boguslavskaya ◽

N. N Chuvatkin ◽

A V Kartashov

Keyword(s):

Carbon Atom ◽

Substitution Reactions ◽

Nucleophilic Substitution Reactions ◽

Halogen Atoms ◽

Oxidative Substitution ◽

New Type ◽

50. Mechanism of substitution at a saturated carbon atom. Part XXXII. The rôle of steric hindrance. (Section G) magnitude of steric effects, range of occurrence of steric and polar effects, and place of the wagner rearrangement in nucleophilic substitution and elimination

10.1039/jr9460000173 ◽

1946 ◽

Vol 0 (0) ◽

pp. 173-194 ◽

Cited By ~ 51

Author(s):

I. Dostrovsky ◽

E. D. Hughes ◽

C. K. Ingold

Keyword(s):

Carbon Atom ◽

Steric Hindrance ◽

Steric Effects ◽

ChemInform Abstract: A Brief Discussion on Nucleophilic Substitution Reaction on Saturated Carbon Atom

ChemInform ◽

10.1002/chin.201433282 ◽

2014 ◽

Vol 45 (33) ◽

pp. no-no

Author(s):

Yan Ding

Keyword(s):

Carbon Atom ◽

Substitution Reaction ◽

Nucleophilic Substitution Reaction ◽

Substitution at a saturated carbon atom. XVII. Organic ion pairs as intermediates in nucleophilic substitution and elimination reactions

Accounts of Chemical Research ◽

10.1021/ar50062a002 ◽

1973 ◽

Vol 6 (2) ◽

pp. 46-53 ◽

Cited By ~ 118

Author(s):

Richard A. Sneen

Keyword(s):

Carbon Atom ◽

Ion Pairs ◽

Elimination Reactions ◽

Mechanism of substitution at a saturated carbon atom. Part XL. Unimolecular nucleophilic substitution and elimination of tert.-butyl bromide with anionic reagents in nitromethane solvent; with some remarks on the addition of acids to olefins

10.1039/jr9540002930 ◽

1954 ◽

pp. 2930 ◽

Cited By ~ 2

Author(s):

P. B. D. de la Mare ◽

E. D. Hughes ◽

C. K. Iingold ◽

Y. Pocker

Keyword(s):

Carbon Atom ◽

Butyl Bromide ◽

Tert Butyl ◽

Mechanism of substitution at a saturated carbon atom. Part XLIX. Analysis of steric and polar effects of alkyl groups in bimolecular nucleophilic substitution, with special reference to halogen exchanges

10.1039/jr9550003200 ◽

1955 ◽

pp. 3200 ◽

Cited By ~ 31

Author(s):

P. B. D. de la Mare ◽

L. Fowden ◽

E. D. Hughes ◽

C. K. Ingold ◽

J. D. H. Mackie

Keyword(s):

Carbon Atom ◽

Special Reference ◽

Alkyl Groups ◽