Long-range chemical interaction in solid-state synthesis: The Kirkendall effect and solid-state reactions in Cu/β-CuZn and Cu/Fe/β-CuZn film systems

Periodic layered morphology may occur during displacement solid-state reactions in ternary (and higher-order) silicide and other material systems. This periodic layered structure consists of regularly spaced layers (bands) of particles of one reaction product embedded in a matrix phase of another reaction product. The number of systems that is known to produce the periodic layered structure is rather small but increasing and includes metal/metal and metal/ceramic semi-infinite diffusion couples. The experimental results on different systems, where the periodic pattern formation has been observed are systematized and earlier explanations for this peculiar diffusion phenomenon are discussed. Formation of the reaction zone morphologies periodic in time and space can be considered as a manifestation of the Kirkendall effect accompanying interdiffusion in the solid state. The patterning during multiphase diffusion is attributed to diverging vacancy fluxes within the interaction zone. This can generate multiple Kirkendall planes, which by attractingin situ-formed inclusions of “secondary-formed phase” can result in a highly patterned microstructure.

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Temperature-Dependent Solid-State Reactions With and Without Kirkendall Effect in Al2O3/ZnO, Fe2O3/ZnO, and CoXOY/ZnO Oxide Thin Film Systems

Advanced Engineering Materials ◽

10.1002/adem.201000043 ◽

2010 ◽

Vol 12 (6) ◽

pp. 509-516 ◽

Cited By ~ 9

Author(s):

Andriy Zolotaryov ◽

Silvana Goetze ◽

Robert Zierold ◽

Dmitri Novikov ◽

Balaji Birajdar ◽

...

Keyword(s):

Thin Film ◽

Solid State ◽

Kirkendall Effect ◽

Oxide Thin Film ◽

Solid State Reactions ◽

Temperature Dependent

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Tailoring the structures and transformations between copper complexes in gas–solid reactions and solid-state synthesis

Inorganic Chemistry Frontiers ◽

10.1039/d0qi00850h ◽

2020 ◽

Vol 7 (22) ◽

pp. 4452-4460

Author(s):

Haitao Li ◽

Ruhui Li ◽

Fang Guo

Keyword(s):

Solid State ◽

Copper Complexes ◽

Solid State Synthesis ◽

Solid State Reactions ◽

Copper Salts

A series of unusual structures and transformations between several copper salts and complexes induced in the solid–gas and solid-state reactions were investigated.

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A General Kinetic-Optical Model for Solid-State Reactions Involving the Nano Kirkendall Effect. The Case of Copper Nanoparticle Oxidation

The Journal of Physical Chemistry C ◽

10.1021/acs.jpcc.6b00137 ◽

2016 ◽

Vol 120 (29) ◽

pp. 16140-16152 ◽

Cited By ~ 16

Author(s):

Mariano D. Susman ◽

Alexander Vaskevich ◽

Israel Rubinstein

Keyword(s):

Solid State ◽

Optical Model ◽

Kirkendall Effect ◽

Solid State Reactions ◽

Copper Nanoparticle

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Studies on solid state reactions of coordination compounds. LXIII. Solid state synthesis of a series of tetranuclear Mo(W)-Ag mixed-metal clusters. Crystal structures of [(n-Bu)4N]3[MoOS3Ag3Br4] and [(n-Bu)4N]3[WS4Ag3Cl4]

Chinese Journal of Chemistry ◽

10.1002/cjoc.19930110506 ◽

2010 ◽

Vol 11 (5) ◽

pp. 418-424 ◽

Cited By ~ 5

Author(s):

Jian-Ping Lang ◽

Xin-Quan Xin ◽

Jin-Hua Cai ◽

Bei-Sheng Kang

Keyword(s):

Solid State ◽

Crystal Structures ◽

Coordination Compounds ◽

Metal Clusters ◽

Solid State Synthesis ◽

Solid State Reactions ◽

Mixed Metal ◽

Mixed Metal Clusters

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Solid-State Synthesis of Coordination Polymers for [2+2] Photoreactions by Grinding

Australian Journal of Chemistry ◽

10.1071/ch09473 ◽

2010 ◽

Vol 63 (4) ◽

pp. 589 ◽

Cited By ~ 9

Author(s):

Mangayarkarasi Nagarathinam ◽

Jagadese J. Vittal

Keyword(s):

Solid State ◽

Coordination Polymers ◽

Solid State Synthesis ◽

Solid State Reactions ◽

Insight Into ◽

Molecular Solid

The feasibility of molecular solid-state reactions by grinding for the synthesis of coordination polymers with aligned trans-1,2-bis(4-pyridyl)ethene ligands suitable for [2+2] photoreaction has been investigated. The results provide an insight into the reactivity of the precursors in the absence of solvents.

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