Synthesis and characterization of metal–polymer nanocomposites with radiation-protective properties

2016 ◽  
Vol 2016 (13) ◽  
pp. 1207-1213 ◽  
Author(s):  
A. N. Bychkov ◽  
G. I. Dzhardimalieva ◽  
G. P. Fetisov ◽  
V. V. Valskiy ◽  
N. D. Golubeva ◽  
...  
Polymers ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 721 ◽  
Author(s):  
Jorge A. Ramírez-Gómez ◽  
Javier Illescas ◽  
María del Carmen Díaz-Nava ◽  
Claudia Muro-Urista ◽  
Sonia Martínez-Gallegos ◽  
...  

Atrazine (ATZ) is an herbicide which is applied to the soil, and its mechanism of action involves the inhibition of photosynthesis. One of its main functions is to control the appearance of weeds in crops, primarily in corn, sorghum, sugar cane, and wheat; however, it is very toxic for numerous species, including humans. Therefore, this work deals with the adsorption of ATZ from aqueous solutions using nanocomposite materials, synthesized with two different types of organo-modified clays. Those were obtained by the free radical polymerization of 4-vinylpyridine (4VP) and acrylamide (AAm) in different stoichiometric ratios, using tetrabutylphosphonium persulfate (TBPPS) as a radical initiator and N,N′-methylenebisacrylamide (BIS) as cross-linking agent. The structural, morphological, and textural characteristics of clays, copolymers, and nanocomposites were determined through different analytical and instrumental techniques, i.e., X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and thermogravimetric analysis (TGA). Adsorption kinetics experiments of ATZ were determined with the modified and synthesized materials, and the effect of the ratio between 4VP and AAm moieties on the removal capacities of the obtained nanocomposites was evaluated. Finally, from these sets of experiments, it was demonstrated that the synthesized nanocomposites with higher molar fractions of 4VP obtained the highest removal percentages of ATZ.


Polymer ◽  
2008 ◽  
Vol 49 (18) ◽  
pp. 4017-4024 ◽  
Author(s):  
Yuung-Ching Sheen ◽  
Chu-Hua Lu ◽  
Chih-Feng Huang ◽  
Shiao-Wei Kuo ◽  
Feng-Chih Chang

2013 ◽  
Vol 62 (11) ◽  
pp. 2509-2513 ◽  
Author(s):  
N. P. Kuznetsova ◽  
T. G. Ermakova ◽  
A. S. Pozdnyakov ◽  
A. I. Emel’yanov ◽  
G. F. Prozorova

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