Effect of methanol, ethanol, and formaldehyde addition on the steam conversion of methane in the presence of nickel catalysts of various porous structure

2006 ◽  
Vol 46 (3) ◽  
pp. 149-158
Author(s):  
L. P. Didenko ◽  
V. I. Savchenko ◽  
V. S. Arutyunov ◽  
L. V. Zav’yalova ◽  
N. A. Chekh ◽  
...  
2019 ◽  
Vol 19 (6) ◽  
pp. 455-464
Author(s):  
R. E. Yakovenko ◽  
V. B. Ilyin ◽  
A. P. Savostyanov ◽  
I. N. Zubkov ◽  
A. V. Dulnev ◽  
...  

The two-step conversion of industrial liquefied hydrocarbon gases (LHG) on NIAP-07-01 (NKM-1) and NIAP-03-01 catalysts for the production of hydrogen-containing gases was investigated. The experiments were carried out in flow reactors with a fixed catalyst bed at a pressure of 0.1 MPa under the following conditions: temperature 350–450 °C, gas hourly space velocity (GHSV) 1000–3000 h–1, steam-gas ratio 4 : 1–8 : 1 (pre-reforming); and temperature 700 °C, GHSV 2000 h–1, air-gas ratio 1.2 : 1 (steam-air reforming). Under the studied conditions, the concentrations of components of the converted gas correspond to the equilibrium values calculated within the Peng-Robinson model. The conversion of methane homologs in the pre-reforming step was found to be virtually 100 %; therewith, the methane concentration reached 32–54 %, and that of hydrogen, 24–47 %. To prevent the formation of elemental carbon (carbonization), pre-reforming of hydrocarbon gases with a high methane equivalent should be performed at H2O : C > 2. In the two-step reforming, the yield of hydrogen-containing gas reaches 15.6 m3 from 1 m3 of the initial LHG with the hydrogen content 41.81 %, and the total content of CO and H2 exceeds 52 %.


2006 ◽  
Vol 79 (4) ◽  
pp. 539-543 ◽  
Author(s):  
V. S. Kolosnitsyn ◽  
S. P. Kosternova ◽  
O. A. Yapryntseva ◽  
A. A. Ivashchenko ◽  
S. V. Alekseev

1989 ◽  
Vol 3 (5) ◽  
pp. 541-543 ◽  
Author(s):  
Eugeniusz Myszka ◽  
Jolanta R. Grzechowiak ◽  
Gerard V. Smith

1979 ◽  
Vol 21 (5) ◽  
pp. 345-346
Author(s):  
A. M. Dubinin ◽  
A. P. Baskakov ◽  
V. B. Shoibonov

2020 ◽  
Vol 94 (9) ◽  
pp. 1962-1964
Author(s):  
A. L. Tarasov ◽  
A. L. Kustov ◽  
A. N. Kalenchuk ◽  
P. V. Sokolovskii ◽  
V. N. Bogdanov ◽  
...  

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