The Length of Substituents on Ligands Regulates the Structural Diversity of Coordination Polymers

2021 ◽  
Vol 47 (12) ◽  
pp. 922-931
Author(s):  
C. L. Zhang ◽  
J. L. Qian ◽  
T. Zhou ◽  
Y. Q. Li
Keyword(s):  
Coordination Polymers ◽  
Structural Diversity

Silver(i) coordination polymers based on halogenated cyanoformamidine: roles of oxyanions and halogen atoms in the structural diversity

CrystEngComm ◽  
2021 ◽  
Vol 23 (9) ◽  
pp. 1961-1968
Author(s):  
Fu-Hung Cheng ◽  
Yu-Hsiang Liu ◽  
Wei-Te Lee ◽  
Ji-Hong Hu ◽  
Hui-Ling Hu ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Structural Diversity ◽  
Halogen Atoms

Halogen substituents on cyanoformamidine ligands and oxyanions affect the structures of complexes due to differences in their electronegativity and volume.

Role of aromatic dicarboxylates in the structural diversity of cobalt(ii) and copper(ii) coordination polymers containing a flexible N,N′-di(3-pyridyl)octanediamide ligand

CrystEngComm ◽  
2013 ◽  
Vol 15 (36) ◽  
pp. 7274 ◽  
Author(s):  
Xiu-Li Wang ◽  
Fang-Fang Sui ◽  
Hong-Yan Lin ◽  
Chuang Xu ◽  
Guo-Cheng Liu ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Structural Diversity

scholarly journals Structural Diversity of Six Coordination Polymers Based on the Designed X-Shaped Ligand 1,1,1,1-Tetrakis[(3-pyridiniourea)methyl]methane

Molecules ◽  
2018 ◽  
Vol 23 (9) ◽  
pp. 2292 ◽  
Author(s):  
Qi-Long Zhang ◽  
Qing Yu ◽  
Hai-Fang Xie ◽  
Bo Tu ◽  
Hong Xu ◽  
...  
Keyword(s):  
Metal Ions ◽  
Single Crystal ◽  
Diffraction Analysis ◽  
Coordination Polymers ◽  
Chain Complex ◽  
Structural Diversity ◽  
Structural Comparison ◽  
Single Crystal Diffraction ◽  
X Ray ◽  
Loop Chain

In this study, six coordination polymers (CPs), {[Ag2(L)(CF3SO3)]·CF3SO3·2H2O·DMF}n (1), {[Ag(L)]·SbF6·4DMF·H2O}n (2), {[Zn(L)0.5(I)2]·3.75H2O}n (3), {[Cd2(L)(I)4(H2O)(DMF)]·4H2O·3DMF}n (4), {[Hg2(L)(I)4]·H2O·4DMF}n (5) and {[Hg2(L)(Cl)4]·2H2O·3DMF}n (6), were obtained based on the designed X-shaped urea-based ligand. X-ray single crystal diffraction analysis revealed that complex 1 displayed a 3D (3,4)-connected {6·82}{64·82}-tcj net. Complex 2 featured a 2D 4-connected {43·63} sheet. Complexes 3 and 5 exhibited a 1D polymeric loop chain. Complex 4 displayed a 1D polymeric fishbone chain. Complex 6 showed a 2D 4-connected {44·62}-sql sheet. Structural comparison revealed that not only the metal ions, but also the anions played crucial roles in the control of final structures.

The construction of Cu(i)/Cu(ii) coordination polymers based on pyrazine–carboxylate: Structural diversity tuned by in situ hydrolysis reaction

CrystEngComm ◽  
2013 ◽  
Vol 15 (26) ◽  
pp. 5359 ◽  
Author(s):  
Zhen-Zhen Wen ◽  
Xi-Ling Wen ◽  
Song-Liang Cai ◽  
Sheng-Run Zheng ◽  
Jun Fan ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Structural Diversity ◽  
Hydrolysis Reaction

Coordination polymers derived from a flexible bis(pyridylurea) ligand: conformational change of the ligand and structural diversity of the complexes

CrystEngComm ◽  
2011 ◽  
Vol 13 (1) ◽  
pp. 215-222 ◽  
Author(s):  
Yongjing Hao ◽  
Biao Wu ◽  
Shaoguang Li ◽  
Chuandong Jia ◽  
Xiaojuan Huang ◽  
...  
Keyword(s):  
Conformational Change ◽  
Coordination Polymers ◽  
Structural Diversity

The structural diversity and photoluminescent properties of cadmium thiophenedicarboxylate coordination polymers

2014 ◽  
Vol 43 (19) ◽  
pp. 7219-7226 ◽  
Author(s):  
Li-Ping Xue ◽  
Xin-Hong Chang ◽  
Shi-Hui Li ◽  
Lu-Fang Ma ◽  
Li-Ya Wang
Keyword(s):  
Thermal Stability ◽  
Coordination Polymers ◽  
Structural Diversity ◽  
Donor Ligands ◽  
Photoluminescence Properties

Two series of Cd(ii) CPs based on two positional isomeric thiophenedicarboxylic acids and N-donor ligands have been synthesized. Moreover, the thermal stability and photoluminescence properties of these complexes are investigated.

Structural diversity of thiodiacetate compounds of group II metals: Synthesis and X-ray characterization of 2D coordination polymers of calcium and strontium

2007 ◽  
Vol 10 (10) ◽  
pp. 1125-1128 ◽  
Author(s):  
Abdessamad Grirrane ◽  
Antonio Pastor ◽  
Eleuterio Álvarez ◽  
Raquel Moyano ◽  
Agustín Galindo
Keyword(s):  
Coordination Polymers ◽  
Structural Diversity ◽  
X Ray ◽  
Group Ii
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