Solvent effect on the kinetics of Beckmann rearrangement

2010 ◽  
Vol 80 (1) ◽  
pp. 31-34 ◽  
Author(s):  
G. G. Midyana ◽  
R. G. Makitra ◽  
E. Ya. Pal’chikova
Keyword(s):  
Solvent Effect ◽  
Beckmann Rearrangement ◽  
Kinetics Of

Kinetics of Ion-Pair Effect of Aquation of Bromopentaammine Cobalt(III) Complex in Different Dicarboxylate Media

2011 ◽  
Vol 324 ◽  
pp. 166-169 ◽  
Author(s):  
Farah Zeitouni ◽  
Gehan El-Subruiti ◽  
Ghassan Younes ◽  
Mohammad Amira
Keyword(s):  
Free Energy ◽  
Solvent Effect ◽  
Compensation Effect ◽  
Ion Pairing ◽  
Reaction Rates ◽  
Ion Pair ◽  
Free Energy Of Activation ◽  
Different Types ◽  
Different Temperatures ◽  
Kinetics Of

The rate of aquation of bromopentaammine cobalt(III) ion in the presence of different types of dicarboxylate solutions containing tert-butanol (40% V/V) have been measured spectrophotometrically at different temperatures (30-600°C) in the light of the effects of ion-pairing on reaction rates and mechanism. The thermodynamic and extrathermodynamic parameters of activation have been calculated and discussed in terms of solvent effect on the ion-pair aquation reaction. The free energy of activation ∆Gip* is more or less linearly varied among the studied dicarboxylate ion-pairing ligands indicating the presence of compensation effect between ∆Hip* and ∆Sip*. Comparing the kip values with respect of different buffers at 40% of ter-butanol is introduced.

Solvent effect on the kinetics of the hydrogenation of n-butyl levulinate to γ-valerolactone

2021 ◽  
Vol 231 ◽  
pp. 116315
Author(s):  
Sarah Capecci ◽  
Yanjun Wang ◽  
Valeria Casson Moreno ◽  
Christoph Held ◽  
Sébastien Leveneur
Keyword(s):  
Solvent Effect ◽  
Kinetics Of

scholarly journals Solvent Effect on the Kinetics of the Basic Hydrolysis of Isatin.

1996 ◽  
Vol 44 (9) ◽  
pp. 1641-1646 ◽  
Author(s):  
Hamed M. ABU EL-NADER ◽  
Mahmoud N. H. MOUSSA
Keyword(s):  
Solvent Effect ◽  
Basic Hydrolysis ◽  
Kinetics Of ◽  
Hydrolysis Of

Solvent effect on the kinetics of the electrooxidation of phenothiazine

1985 ◽  
Vol 30 (10) ◽  
pp. 1301-1306 ◽  
Author(s):  
M. Opało ◽  
A. Kapturkiewicz
Keyword(s):  
Solvent Effect ◽  
Kinetics Of
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