dynamic solvent effect
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scholarly journals Impact of the macrocyclic structure and dynamic solvent effect on the reactivity of a localised singlet diradicaloid with π-single bonding character

2021 ◽  
Author(s):  
Zhe Wang ◽  
Rikuo Akisaka ◽  
Sohshi Yabumoto ◽  
Tatsuo Nakagawa ◽  
Sayaka Hatano ◽  
...  
Keyword(s):  
Solvent Effect ◽  
Coupling Reaction ◽  
Dynamic Effects ◽  
Radical Coupling ◽  
Dynamic Solvent Effect ◽  
Radical Coupling Reaction ◽  
Macrocyclic Structure

An extremely long-lived localised singlet diradical with π-single bonding character is found in a macrocyclic structure that retards the radical–radical coupling reaction by the “stretch and solvent-dynamic effects”.

Dynamic solvent effects in radical–radical coupling reactions: an almost bottleable localised singlet diradical

2020 ◽  
Vol 22 (48) ◽  
pp. 27949-27954 ◽  
Author(s):  
Rikuo Akisaka ◽  
Yasushi Ohga ◽  
Manabu Abe
Keyword(s):  
High Pressure ◽  
Solvent Effect ◽  
Solvent Effects ◽  
Coupling Reactions ◽  
Radical Coupling ◽  
Dynamic Solvent Effect

The lifetime of a localised singlet diradical with bulky substituents was extended using the dynamic solvent effect and reached an almost bottleable timescale of ∼2 s under extremely viscous conditions induced by high pressure.

scholarly journals First Observation for Dynamic Solvent Effect in Ionic Liquids

2016 ◽  
Vol 45 (4) ◽  
pp. 385-387
Author(s):  
Satoshi Kitaoka ◽  
Kaoru Nobuoka ◽  
Junji Miura ◽  
Yasushi Ohga ◽  
Yuichi Ishikawa
Keyword(s):  
Ionic Liquids ◽  
Solvent Effect ◽  
Dynamic Solvent Effect

Activationless dynamic solvent effect

2007 ◽  
Vol 447 (1-3) ◽  
pp. 162-167 ◽  
Author(s):  
Serguei Feskov ◽  
Vladislav Gladkikh ◽  
Anatoly I. Burshtein
Keyword(s):  
Solvent Effect ◽  
Dynamic Solvent Effect

Observation of Dynamic Solvent Effect for Electron Tunneling in U-Shaped Molecules

2004 ◽  
Vol 126 (34) ◽  
pp. 10778-10786 ◽  
Author(s):  
Min Liu ◽  
David H. Waldeck ◽  
Anna M. Oliver ◽  
Nicholas J. Head ◽  
Michael N. Paddon-Row
Keyword(s):  
Solvent Effect ◽  
Electron Tunneling ◽  
Dynamic Solvent Effect

Chemo- and Enzyme-Catalyzed Reactions Revealing a Common Temperature-Dependent Dynamic Solvent Effect on Enantioselectivity

2003 ◽  
Vol 86 (11) ◽  
pp. 3548-3559 ◽  
Author(s):  
Gianfranco Cainelli ◽  
Paola Galletti ◽  
Daria Giacomini ◽  
Andrea Gualandi ◽  
Arianna Quintavalla
Keyword(s):  
Solvent Effect ◽  
Temperature Dependent ◽  
Dynamic Solvent Effect ◽  
Catalyzed Reactions ◽  
Enzyme Catalyzed Reactions
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