Reaction of Zirconium Tetrachloride with 2,2-Dimethylbutanoic Acid

2018 ◽  
Vol 88 (7) ◽  
pp. 1430-1435
Author(s):  
B. D. Makhaev ◽  
L. A. Petrova
Keyword(s):  
Zirconium Tetrachloride

CO-ORDINATION COMPLEXES OF TITANIUM (IV) HALIDES: II. PREPARATION AND INFRARED SPECTRA OF THE COMPLEXES OF TITANIUM TETRACHLORIDE WITH DIESTERS OF α,ω-DICARBOXYLIC ACIDS AND COMPARISON WITH ANALOGOUS COMPLEXES OF ZIRCONIUM TETRACHLORIDE AND TIN TETRACHLORIDE

1961 ◽  
Vol 39 (11) ◽  
pp. 2343-2352 ◽  
Author(s):  
Ernest Rivet ◽  
Real Aubin ◽  
Roland Rivest
Keyword(s):  
Molecular Weight ◽  
Infrared Spectra ◽  
Titanium Tetrachloride ◽  
Complex Molecule ◽  
Dicarboxylic Acids ◽  
The Other ◽  
Zirconium Tetrachloride ◽  
Melting Points ◽  
Zirconium Complexes ◽  
Tin Tetrachloride

Co-ordination complexes between diesters of α,ω-dicarboxylic acids and titanium tetrachloride, tin tetrachloride, and zirconium tetrachloride have been prepared. The analytical results, the infrared spectra, the melting points, and the molecular-weight determinations indicate that for the titanium and zirconium complexes, two types of complexes are obtained, one having a general formula MX4•1 diester in which chelate rings from five to nine atoms are formed and the other one, 2MX4•1 diester in which there are two 4-membered rings per complex molecule. With tin tetrachloride only one type of complex is formed, which has two tin tetrachlorides and two diesters per complex molecule.

scholarly journals Hydrocarbon Activation with Metal Halides:  Zirconium Tetrachloride Catalyzing the Jacobsen Reaction and Assisting the Trimerization of Alkynes via the Formation of η6-Arene−Zirconium(IV) Complexes

1998 ◽  
Vol 17 (2) ◽  
pp. 274-274 ◽  
Author(s):  
Fabrizio Musso ◽  
Euro Solari ◽  
Carlo Floriani ◽  
Kurt Schenk ◽  
Angiola Chiesi-Villa ◽  
...  
Keyword(s):  
Metal Halides ◽  
Zirconium Tetrachloride

Optimisation of anaerobic stabilised leachate treatment using catalytic ozonation with zirconium tetrachloride

2018 ◽  
Vol 21 (2/3) ◽  
pp. 102
Author(s):  
Siti Nor Farhana Zakaria ◽  
Hamidi Abdul Aziz ◽  
Salem S. Abu Amr ◽  
Yung Tse Hung
Keyword(s):  
Catalytic Ozonation ◽  
Zirconium Tetrachloride ◽  
Leachate Treatment

Notizen: Die Umylidierungsreaktion von Zirkoniumtetrachlorid mit Phosphonium-yliden: Struktur von Methyl-tris(diethylamino)- phosphonium-Hexachlorozirkonat / The Transylidation Reaction of Zirconium tetrachloride with Phosphonium Ylides: Structure of Methyl-tris(diethylamino)- phosphonium Hexachlorozirconate

1986 ◽  
Vol 41 (3) ◽  
pp. 395-398 ◽  
Author(s):  
Hubert Schmidbaur ◽  
Reinhard Pichl ◽  
Gerhard Muller
Keyword(s):  
Single Crystal ◽  
Complex Salt ◽  
X Ray Diffraction ◽  
Zirconium Tetrachloride ◽  
X Ray

The reaction between ZrCl4 and (Et2N)3P=CH2 affords the zirconium-substituted vlide [(Et2N)3PCZrCl2]2 (1). The transylidation by-pro­duct [(Et2N)3PCH3]Cl is trapped by excess ZrCl4 to give the complex salt [(Et2N)3PCH3]2ZrCl6 (2) the structure of which was determined by single crystal X-ray diffraction.

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