A theoretical model of dissolution and hydrate formation processes in shock waves

2009 ◽  
Vol 18 (1) ◽  
pp. 1-7 ◽  
Author(s):  
V. E. Dontsov ◽  
V. E. Nakoryakov ◽  
A. A. Chernov
Water ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 52
Author(s):  
Xiang He ◽  
Sijia Wang ◽  
Bingjian Zhang

Dew is a common but important phenomenon. Though water is previously considered to be a threat to earthen heritage sites, artificial dew is showing potential in relic preservation. A model of dew prediction on earthen sites will be essential for developing preventive protection methods, but studies of dew formation processes on relics are limited. In this study, a two parameter model is proposed. It makes approximations according to the features of earthen heritage sites, assuming that a thin and steady air layer exists close to the air–solid interface. This semi-theoretical model was based on calculations of the mass transfer process in the air layer, and was validated by simulations of laboratory experiments (R > 0.9) as well as field experiments. Additionally, a numerical simulation, performed by the commercial software COMSOL, confirmed that the difference between fitting parameter δ and the thickness of assumed mass transfer field was not significant. This model will be helpful in developing automatic environmental control systems for stabilizing water and soluble salts, thus enhancing preventive protection of earthen heritage sites.


SPE Journal ◽  
2016 ◽  
Vol 22 (03) ◽  
pp. 746-755 ◽  
Author(s):  
T.. Shimizu ◽  
Y.. Yamamoto ◽  
N.. Tenma

Summary Offshore natural-gas production from methane-hydrate (MH) reservoirs has received considerable attention. In this study, the offshore production method is briefly described, followed by the flow loop experiments performed to investigate the formation processes of MH in methane-in-water bubbly flows. Transient processes of phase transformation are characterized by phase paths, flow morphologies, pump heads, and in-situ particle-size measurements. It is realized that an MH slurry is generated by MH shells covering unconverted bubbles, whereas it can be transformed into a colloidal flow with fine crystalline particles under an intense turbulent shear. This study suggests that, in practice, the flow pattern under MH formation would be determined by the phase path and the flow velocity in the pipeline, which is one of the important factors considered in the evaluation of flow-assurance risks.


2020 ◽  
Author(s):  
Jose Rodriguez-Martinez ◽  
Alvaro Vaz-Romero ◽  
Tiago dos Santos

This paper investigates the steady-state elastoplastic fields induced by a pressurized cylindrical cavity expanding dynamically in an anisotropic porous medium. For that task, we have developed a theoretical model which: (i) incorporates into the formalism developed by Cohen and Durban (2013b) the effect of plastic anisotropy using the constitutive framework developed by Benzerga and Besson (2001) and (ii) uses the artifical viscosity approach developed by Lew et al. (2001) to capture the shock waves that emerge at high cavity expansion velocities. We have shown that while the development of the shock waves is hardly affected by the material anisotropy, the directionality of the plastic properties does have an effect on the elastoplastic fields that evolve near the cavity. The importance of this effect is strongly dependent on the cavity expansion velocity, the initial porosity and the strain hardening of the material. In addition, the theoretical model has been used in conjunction with the Recht and Ipson (1963) formulas to assess the ballistic performance of porous anisotropic targets against high velocity perforation.


2019 ◽  
Vol 238 ◽  
pp. 195-201 ◽  
Author(s):  
Ze-Yu Li ◽  
Zhi-Ming Xia ◽  
Zhao-Yang Chen ◽  
Xiao-Sen Li ◽  
Chun-Gang Xu ◽  
...  

2019 ◽  
Vol 158 ◽  
pp. 5850-5855 ◽  
Author(s):  
Zhiming Xia ◽  
Zeyu Li ◽  
Xiaosen Li ◽  
Zhaoyang Chen ◽  
Gang Li ◽  
...  

Author(s):  
Remi-Erempagamo T. Meindinyo ◽  
Thor Martin Svartås

The thermodynamics and kinetics of clathrate hydrate formation processes are topics of high scientific interest, especially in the petroleum industry. Researchers have made efforts at understanding the underlying processes that explicate the macroscopic observations from experiments and other research methods of gas hydrate formation. To achieve this, they have employed theories founded upon force related intermolecular interactions. Some of the theories and concepts employed include hydrogen bonding, the Leonard Jones force principle, and steric interactions. This paper gives a brief review of how these intermolecular interaction principles have been understood, and used as tools, in explaining the inaccessible microscopic processes, that characterize clathrate hydrate formation. It touches upon nucleation, growth, and inhibition processes.


2022 ◽  
pp. 413-429
Author(s):  
Fateme Etebari ◽  
Yasaman Enjavi ◽  
Mohammad Amin Sedghamiz ◽  
Mohammad Reza Rahimpour

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