An engineering model for high-speed switching in GeSbTe phase-change memory

Ge2Sb2Te5 is the most successful phase-change alloy in non-volatile memory using the amorphous-crystal phase transition. In deriving further high performance in switching, especially SET speed (from amorphous to crystal transition) should still be modified. In this work, It was examined an ideal Ge2Sb2Te5 alloy based on the Kolobov model using ab-initio molecular dynamics simulations. As a result, it was cleared that a uniaxial exchange between vacancies and Ge atoms is the crucial role in realizing high-speed switching and a large contrast in the resonance bonding state in the alloy. The vacancy engineering enables the alloy switching speed extremely faster.

Self-evolving materials based on metastable-to-stable crystal transition of polymorphic polyolefin

Living organisms can self-evolve with time in order to adapt to natural environment. Analogically, self-evolving materials also show similar properties based on a non-equilibrium structural transformation. The common design of...

Investigation on the α/δ Crystal Transition of Poly(l-lactic Acid) with Different Molecular Weights

Poly(l-lactic acid) (PLLA) crystal possesses a complex polymorphism, and the formation mechanism of various crystal forms has been a hot research topic in the field of polymer condensate matter. In this research, five kinds of PLLA with different molecular weights were prepared by ring-opening polymerization with strict dehydration operations and multistep purification treatments. Then, thin film isothermal crystallization experiments were carried out to obtain crystallized samples. Previous research has proven that the PLLA α crystal form is usually formed at a temperature above 120 °C and the PLLA δ (or α’) crystal form is usually formed at a temperature below 120 °C. However, in this research, the characterization results indicated that the PLLA crystal changed from δ form to α form with the decrease of molecular weight at a temperature of 80 °C. Considering the molecular weight effect, the paper argued that the transitions of the α/δ crystal form are not only associated with temperature, but also related to entanglement state before crystallization. The small-angle X-ray scattering of the PLLA crystal and rheology analysis of the PLLA melt before crystallization further proved the significant role of entanglement. Finally, we tentatively proposed the entanglement effect mechanism on the transitions of the α/δ crystal form.

Strain-Induced Form Transition and Crystallization Behavior of the Transparent Polyamide

A transparent polyamide, poly(4,4′-aminocyclohexyl methylene dodecanedicarboxylamide) (PAPACM12), was studied and characterized by in situ wide-angle X-ray diffraction (WAXD) to establish the relationship between its crystallization behavior, crystalline form transition under external fields, and macroscopic properties. During the heating process, cold crystallization occurred and increased, and there was no form transition below the melting point. During the isothermal process, PAPACM12 exhibited the same crystalline structure as that during the heating process. The crystalline structure of PAPACM12 was attributed to α-form crystal, which is the stable form, according to the WAXD diffraction peaks of the conventional AABB-type polyamides. During stretching deformation, the crystal transition from α-form to γ-form and strain-induced crystallization were observed to contribute to the PAPACM12 with higher breaking strength and elongation. This study firstly determine the crystalline structure of transparent polyamides, and then the controlled strain-induced crystallization and transformation are demonstrated to be effective preparation methods for polyamides with high properties.