Common Processes of the Hydration of Chloroacetic Acids

2021 ◽  
Vol 15 (2) ◽  
pp. 228-232
Author(s):  
E. S. Vasiliev ◽  
G. V. Karpov ◽  
N. D. Volkov ◽  
I. I. Morozov ◽  
S. V. Savilov
Keyword(s):  
Chloroacetic Acids

scholarly journals Natural Formation and Degradation of Chloroacetic Acids and Volatile Organochlorines in Forest Soil. Challenges to understanding (12 pp)

2005 ◽  
Vol 12 (4) ◽  
pp. 233-244 ◽  
Author(s):  
Frank Laturnus ◽  
Isabelle Fahimi ◽  
Milan Gryndler ◽  
Anton Hartmann ◽  
Mathew Heal ◽  
...  
Keyword(s):  
Forest Soil ◽  
Chloroacetic Acids ◽  
Natural Formation

scholarly journals Formation of chloroacetic acids and chloral hydrate from humic substances during aqueous chlorination.

1986 ◽  
Vol 9 (7) ◽  
pp. 437-444
Author(s):  
Kunio SUGINO ◽  
Sueo NISHI ◽  
Reiko OHURA ◽  
Yoshiyuki HORIMOTO
Keyword(s):  
Humic Substances ◽  
Chloral Hydrate ◽  
Chloroacetic Acids

The fate and persistence of trifluoroacetic and chloroacetic acids in pond waters

Chemosphere ◽  
2001 ◽  
Vol 42 (3) ◽  
pp. 309-318 ◽  
Author(s):  
David A Ellis ◽  
Mark L Hanson ◽  
Paul K Sibley ◽  
Tazeen Shahid ◽  
Neil A Fineberg ◽  
...  
Keyword(s):  
Chloroacetic Acids

Studies on the rearrangement of (trichloromethyl)carbinols to α-chloroacetic acids

1980 ◽  
Vol 58 (5) ◽  
pp. 485-493 ◽  
Author(s):  
Wilkins Reeve ◽  
James R. McKee ◽  
Robert Brown ◽  
Sitarama Lakshmanan ◽  
Gertrude A. McKee
Keyword(s):  
Carbon Monoxide ◽  
Potassium Hydroxide ◽  
Potential Importance ◽  
Chloroacetic Acids ◽  
Aqueous Potassium Hydroxide ◽  
Mechanism Of The Reaction

Phenyl(trichloromethyl)carbinol undergoes an unimolecular, predominantly intramolecular conversion into potassium α-chlorophenylacetate on stirring with 10 % aqueous potassium hydroxide at 0 °C for several days. Besides providing an interesting example of a 1–2 chlorine shift, the reaction is of potential importance for the synthesis of α-chloro acids. The study of a variety of (trichloromethyl)carbinols shows the reaction is general for secondary (trichloromethyl)carbinols as well as trichloroethanol. The mechanism of the reaction involves the preliminary formation of an epoxide. Several mechanisms are considered for the conversion of the epoxide to the α-chloroacetate anion, but none accounts for all of the experimental facts. Tertiary carbinols break down at the epoxide stage into a ketone and carbon monoxide.

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