Liquid-vapour equilibrium. XLI. The system isopropyl alcohol-water-toluene at 760 torr

1970 ◽  
Vol 35 (1) ◽  
pp. 1-12 ◽  
Author(s):  
L. Staňková ◽  
F. Veselý ◽  
J. Pick
Keyword(s):  
Isopropyl Alcohol ◽  
Alcohol Water

ChemInform Abstract: Platinum on Carbon-Catalyzed Hydrodefluorination of Fluoroarenes Using Isopropyl Alcohol-Water-Sodium Carbonate Combination.

ChemInform ◽  
2012 ◽  
Vol 43 (32) ◽  
pp. no-no
Author(s):  
Yoshinari Sawama ◽  
Yuki Yabe ◽  
Masahiro Shigetsura ◽  
Tsuyoshi Yamada ◽  
Saori Nagata ◽  
...  
Keyword(s):  
Sodium Carbonate ◽  
Isopropyl Alcohol ◽  
Alcohol Water

scholarly journals Synthesis of tetraalkyl thiuram disulfides using different oxidants in recycling solvent mixture

2012 ◽  
Vol 18 (1) ◽  
pp. 73-81 ◽  
Author(s):  
Milutin Milosavljevic ◽  
Aleksandar Marinkovic ◽  
Jelena Markovic ◽  
Danijela Brkovic ◽  
Milan Milosavljevic
Keyword(s):  
Isopropyl Alcohol ◽  
Level Structure ◽  
Reaction Medium ◽  
Solvent Mixture ◽  
Azeotropic Mixture ◽  
Water Mixture ◽  
Alcohol Water ◽  
High Yields ◽  
Industrial Level ◽  
Laboratory Synthesis

A new optimized laboratory synthesis of tetraalkyl thiuram disulfides, starting from dialkyl amines and carbon disulfide in presence of three oxidants (hydrogen peroxide, potassium peroxodisulfate and sodium hypochlorite) and appropriate reaction medium: two mixtures of isopropyl alcohol - water used in two consecutive syntheses, was presented in this work. First synthesis was performed in a recycled azeotropic mixture of isopropyl alcohol - water 87.7% - 12.3%, and second in a filtrate obtained after first synthesis, which was a mixture of isopropyl alcohol - water 70.4% - 29.6%. After the second synthesis and filtration, recycled azeotropic mixture isopropyl alcohol - water 87.7% - 12.3% was regenerated from the filtrate by rectification. Considering this, the technology for beneficial use of recycling isopropyl alcohol - water mixture as reaction medium for tetraalkyl thiuram disulfides synthesis was developed. Such concept contributes to extraordinary economical benefit of implemented optimal laboratory synthesis at semi-industrial level. High yields of tetraalkyl thiuram disulfides syntheses were obtained at both laboratory and semiindustrial level. Structure and purity of synthesized compounds were confirmed by elemental analysis, as well as FTIR, 1H and 13C NMR, and MS spectral data.

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