Effect of particle size distribution on the kinetics of solid phase-gas reactions

1975 ◽  
Vol 40 (4) ◽  
pp. 1119-1125 ◽  
Author(s):  
J. Skřivánek ◽  
J. Šubrt
2011 ◽  
Vol 477 ◽  
pp. 118-124
Author(s):  
Bao Lin Zhu ◽  
Xin Huang ◽  
Ye Guo

On the basis of the principle for the highest filling degree of cement hydrates, it is synthetically considered that a matching connection between hydration of cement, volume increment of solid phase and packing density of cement paste, a calculation method for a connection between cement continuous particle size distribution and strength of hardened cement paste is developed and tested by experiment. Based on above-mentioned analysis, a tentative research on the effect of particle size distribution of cement on strength is carried out.


1986 ◽  
Vol 85 ◽  
Author(s):  
James M. Pommersheim

ABSTRACTA general method has been developed for determining the effects of particle size distribution (PSD) on the kinetics of hydration. Given the PSD and the kinetic rate for particles having a single size, expressions can be derived for the variation of the total degree of hydration with time. The method was applied to PSD and kinetic functions typical of cement systems that account for reaction, diffusion and expansion of spherical hydrate layers. The PSD was found to critically affect the kinetics. A key feature of the theory follows with time those particles that have become totally hydrated, so-called “dead” particles. This produces a dead-particle hydration curve having approximately the same shape and location as the overall hydration curve. It can be represented analytically in all cases and gives a measure of the disguise provided by the distribution.


2011 ◽  
Vol 194-196 ◽  
pp. 1007-1011
Author(s):  
Bao Lin Zhu ◽  
Xin Huang ◽  
Ye Guo

On the basis of the principle for the highest filling degree of cement hydrates, it is synthetically considered that a matching connection between hydration of cement, volume increment of solid phase and packing density of cement paste, a calculation method for a connection between cement continuous particle size distribution and strength of cement paste is developed and tested by experiment. Based on above-mentioned analysis, a tentative research on the effect of particle size distribution of cement on strength is carried out.


2017 ◽  
Vol 184 ◽  
pp. 240-247 ◽  
Author(s):  
A. Norori-McCormac ◽  
P.R. Brito-Parada ◽  
K. Hadler ◽  
K. Cole ◽  
J.J. Cilliers

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