Formation of Reactive Clusters in Pd-Y Zeolite by Reduction-Reoxidation Treatment
1992 ◽
Vol 57
(4)
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pp. 817-825
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Keyword(s):
X Ray
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Preparation of a finely dispersed Pd-Y zeolite has been investigated by temperature-programmed reduction (TPR) and extended X-ray absorption fine structure (EXAFS) techniques. Upon the treatment by a sequence of calcination, reduction, and reoxidation, the original Pd(NH3)42+ ions in the zeolite transformed to reactive species, which were reduced with hydrogen at room temperature and characterized as small PdO clusters of about 25 Pd atoms.
1997 ◽
Vol 7
(C2)
◽
pp. C2-67-C2-81
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1978 ◽
Vol 39
(C4)
◽
pp. C4-120-C4-124
1986 ◽
Vol 261
(13)
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pp. 5689-5692
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