Kinetics of Zinc(II) Reduction at the Hg Electrode in WaterEthanol Mixtures

1994 ◽  
Vol 59 (7) ◽  
pp. 1545-1550 ◽  
Author(s):  
Barbara Marczewska

The kinetics of the Zn(II)-Zn(Hg) electrode process was studied in water ethanol NaClO4 mixtures. Diffusion coefficients, formal potential and charge transfer rate constants were determined. The results are interpreted taking into account the change of the activation energy of the process.

2021 ◽  
Vol 12 (2-2021) ◽  
pp. 60-65
Author(s):  
D. A. Vetrova ◽  
◽  
S. A. Kuznetsov ◽  

The influence of the second coordination sphere of titanium complexes on the charge transfer kinetics of the Ti (IV)/Ti (III) redox couple in melts of alkali metal halides was studied by cyclic voltammetry method. Diffusion coefficients in the CsC-CsF (10 wt. %) melt were calculated. The standard rate constants of charge transfer have been determined by the Nicholson method. The activation energies of the charge transfer process in (NaCl- KCl)equimol-NaF (10 wt. %) — K2TiF6, KCl-KF (10 wt. %) — K2TiF6 and CsCl-CsF (10 wt. %) — K2TiF6 melts were calculated.


ChemSusChem ◽  
2016 ◽  
Vol 9 (13) ◽  
pp. 1647-1659 ◽  
Author(s):  
Katarzyna Pydzińska ◽  
Jerzy Karolczak ◽  
Ivet Kosta ◽  
Ramon Tena-Zaera ◽  
Anna Todinova ◽  
...  

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