Influence of DNA on the Reaction Rate of an Electron Transfer Process: A Kinetic Study of the Reaction Between [Co(Pyrazinecarboxylate)(NH3)4]2+ and [Fe(CN)6]4- in Aqueous Solutions in the Presence of DNA
2002 ◽
Vol 67
(8)
◽
pp. 1165-1172
◽
Keyword(s):
The kinetics of the electron transfer reaction between tetraammine(pyrazinecarboxylate)cobalt(III), [Co(pyrazinecarboxylate)(NH3)4]2+, and hexacyanoferrate(II), [Fe(CN)6]4- was studied in aqueous solutions in the presence of DNA at concentrations 0-2.28 · 10-3 mol dm-3. A decrease in the rate constant with increasing DNA concentration was observed. The results are interpreted on the basis of the pseudophase model. The meaning of its parameters for the second-order reaction is discussed.
2001 ◽
Vol 114
(22)
◽
pp. 9959-9968
◽
Keyword(s):
1968 ◽
Vol 90
(14)
◽
pp. 3611-3618
◽
Keyword(s):
2011 ◽
Vol 440
(1)
◽
pp. 234-238
◽
2013 ◽
Vol 79
(3-4)
◽
pp. 425-435
◽