The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate
Keyword(s):
The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate (soman) was examined with a series of alkoxides and in corresponding alcohols: methanol, ethanol, 1-propanol, 2-propanol, 2-methoxyethanol and 2-ethoxyethanol. Soman reacts with the used alkoxides in a second order reaction, first order in each reactant. The kinetics of the reaction between 1,2,2-trimethylpropyl-methylfluorophosphonate and ethanol in the presence of diethylenetriamine was also examined. A third order reaction rate constant was calculated, first order in each reactant. The activation energy, frequency factor and activation entropy were determined on the basis of the kinetic data.
Keyword(s):
Keyword(s):
Keyword(s):
2013 ◽
Vol 850-851
◽
pp. 82-85
1993 ◽
Vol 58
(3)
◽
pp. 538-546
◽
Keyword(s):
2004 ◽
Vol 69
(10)
◽
pp. 1877-1888
Keyword(s):
Keyword(s):
Keyword(s):