Classical Analytical Description of Negative Hydrogen Ions

Author(s):  
E. Oks

Studies of negative hydrogen ions (hereafter, NHI), such as, H– and D–, are important from both practical and fundamental points of view. One of the reasons for practical importance has to do with heating tokamak plasmas by external beams of NHI. Another practical use is the injection of NHI in high power proton accelerator facilities – for enhancing their performance. In addition, NHI are also important for studies of opacities of the atmospheres of the Sun and of the A-type stars. We present a classical analytical description of NHI in the situation where the underlying hydrogen (or deuterium) atom constitutes a rapid subsystem while the outer electron represents a slow subsystem. We focus at the case where the inner electron is in a circular state, so that the subsystem “nucleus plus inner electron” does not have the average electric dipole moment – in distinction to previous studies where the presence of the average dipole moment was the crucial requirement. By using the separation of rapid and slow subsystems, we show analytically that there is a classical bound state in such system and studied its parameters. In particular, we calculate analytically the primary frequency of the radiation of such system. This could be used for its experimental detection. The states that we found for the above systems could be considered as classical counterparts of the double-excited states of NHI previously studied in the literature in frames of quantum mechanics. The existence of classical counterparts of the double-excited states of NHI is a counterintuitive result.

1985 ◽  
Vol 40 (9) ◽  
pp. 913-919
Author(s):  
Juan Carlos López ◽  
José L. Alonso

Abstract The rotational transitions of 3,4-dihydro-1,2-pyran in the ground state and six vibrationally excited states have been assigned. The rotational constants for the ground state (A = 5198.1847(24), B = 4747.8716(24) and C = 2710.9161(24) have been derived by fitting μa, μb and μc-type transitions. The dipole moment was determined from Stark displacement measurements to be 1.400(8) D with its principal axis components |μa| =1.240(2), |μb| = 0.588(10) and |μc| = 0.278(8) D. A model calculation to reproduce the ground state rotational constants indicates that the data are consistent with a twisted ring conformation. The average intensity ratio gives vibrational separations between the ground and excited states of the ring-bending and ring-twisting modes of ~ 178 and ~ 277 cm-1 respectively.


2008 ◽  
Vol 57 (6) ◽  
pp. 1166-1171 ◽  
Author(s):  
G. V. Loukova ◽  
A. A. Milov ◽  
V. P. Vasiliev ◽  
V. A. Smirnov
Keyword(s):  

Author(s):  
Philip Coppens

The moments of a charge distribution provide a concise summary of the nature of that distribution. They are suitable for quantitative comparison of experimental charge densities with theoretical results. As many of the moments can be obtained by spectroscopic and dielectric methods, the comparison between techniques can serve as a calibration of experimental and theoretical charge densities. Conversely, since the full charge density is not accessible by the other experimental methods, the comparison provides an interpretation of the results of the complementary physical techniques. The electrostatic moments are of practical importance, as they occur in the expressions for intermolecular interactions and the lattice energies of crystals. The first electrostatic moment from X-rays was obtained by Stewart (1970), who calculated the dipole moment of uracil from the least-squares valence-shell populations of each of the constituent atoms of the molecule. Stewart’s value of 4.0 ± 1.3 D had a large experimental uncertainty, but is nevertheless close to the later result of 4.16 ± 0.4 D (Kulakowska et al. 1974), obtained from capacitance measurements of a solution in dioxane. The diffraction method has the advantage that it gives not only the magnitude but also the direction of the dipole moment. Gas-phase microwave measurements are also capable of providing all three components of the dipole moment, but only the magnitude is obtained from dielectric solution measurements. We will use an example as illustration. The dipole moment vector for formamide has been determined both by diffraction and microwave spectroscopy. As the diffraction experiment measures a continuous charge distribution, the moments derived are defined in terms of the method used for space partitioning, and are not necessarily equal. Nevertheless, the results from different techniques agree quite well. A comprehensive review on molecular electric moments from X-ray diffraction data has been published by Spackman (1992). Spackman points out that despite a large number of determinations of molecular dipole moments and a few determinations of molecular quadrupole moments, it is not yet widely accepted that diffraction methods lead to valid experimental values of the electrostatic moments.


2020 ◽  
Vol 2020 (10) ◽  
Author(s):  
V. V. Flambaum ◽  
I. B. Samsonov ◽  
H. B. Tran Tan

Abstract Experiments with paramagnetic ground or metastable excited states of molecules (ThO, HfF+, YbF, YbOH, BaF, PbO, etc.) provide strong constraints on the electron electric dipole moment (EDM) and the coupling constant CSP of contact semileptonic interaction. We compute new contributions to CSP arising from the nucleon EDMs due to the combined electric and magnetic electron-nucleon interaction. This allows us to improve limits from the experiments with paramagnetic molecules on the CP-violating parameters, such as the proton EDM, |dp| < 1.1 × 10−23e·cm, the QCD vacuum angle, $$ \left|\overline{\theta}\right| $$ θ ¯ < 1.4 × 10−8, as well as the quark chromo-EDMs and the π-meson-nucleon couplings. Our results may also be used to search for the axion dark matter which produces oscillating $$ \overline{\theta} $$ θ ¯ .


2011 ◽  
Vol 20 (supp02) ◽  
pp. 200-209
Author(s):  
CÉSAR A. Z. VASCONCELLOS ◽  
DIMITER HADJIMICHEF ◽  
MÁRIO L. L. DA SILVA ◽  
MOISÉS RAZEIRA ◽  
ALEXANDRE MESQUITA ◽  
...  

We investigate relativistic bound states for a hypothetical light scalar gluino pair (gluinonium), in the framework of the covariant Bethe-Salpeter equation (BSE). In this paper, we derive, from the covariant BSE for a fermion-anti-fermion system, using charge conjugation, the corresponding bound-state equation for a gluino pair and we then formulate, for a static harmonic kernel, the coupled differential equations for the corresponding static Bethe-Salpeter amplitude. The steps of our approach then include a numerical solution of the Bethe-Salpeter amplitude for a two-body interaction consisting of scalar, pseudo-scalar, and four-vector components and the determination of the energy spectrum for the ground and the radially excited states of massive gluinonium. We found the energy spectrum and radial distributions of fundamental and excited states of gluinonium. The comparison of the values obtained in the extreme relativistic case with the corresponding values predicted by a harmonic oscillator potential model shows that there is good agreement between the two formulations. The predictions of the binding energy of glunionium in the non-relativistic model are however systematically higher.


2003 ◽  
Vol 119 (6) ◽  
pp. 3130-3137 ◽  
Author(s):  
Alexei M. Frolov ◽  
Vedene H. Smith
Keyword(s):  

2012 ◽  
Vol 546 ◽  
pp. 24-29 ◽  
Author(s):  
Tadeusz Pluta ◽  
Maciej Kolaski ◽  
Miroslav Medved’ ◽  
Šimon Budzák
Keyword(s):  

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