Kimberlites from the Wawa area, Ontario

2002 ◽  
Vol 39 (12) ◽  
pp. 1819-1838 ◽  
Author(s):  
Felix V Kaminsky ◽  
Sergei M Sablukov ◽  
Ludmila I Sablukova ◽  
Vladimir S Shchukin ◽  
Dante Canil

Two newly discovered kimberlites from the Wawa area, Ontario, are Group-1 kimberlites in their petrographic, mineralogical, geochemical, and isotopic features. They contain mantle minerals and xenoliths of the Fe–Ti-association (magnesian ilmenite, iron-rich olivine, orange Ti-pyrope garnet, augite, and ferroan enstatite) and of the Cr-association (chromian spinel, forsteritic olivine, purple Cr-pyrope garnets, chromian diopside, and enstatite); minerals of Fe–Ti-association are much more abundant. Minerals of eclogitic association are absent. Both G-10 pyrope garnets and high Cr spinels typically associated with diamond are represented in the Cr-association. The average age of the kimberlites is 1097 ± 7 Ma; i.e., contemporaneous with other alkaline igneous rocks in the Wawa area. Equilibration pressures and temperatures of mantle xenoliths plot close to a 40–45 mW m–2 geotherm. On the basis of the Ni-in-garnet geothermometer, garnets from the Wawa kimberlites equilibrated at 800–1350°C, and at least in part within the diamond stability field. It is likely that kimberlitic magma was derived from light rare earth-element-enriched asthenospheric mantle.

2015 ◽  
Vol 3 (40) ◽  
pp. 10566-10573 ◽  
Author(s):  
Yufei Hu ◽  
Sabah K. Bux ◽  
Jason H. Grebenkemper ◽  
Susan M. Kauzlarich

ThezTof Yb14MnSb11is improved by the introduction of a light rare earth element, RE3+(RE = Pr, Sm) with partially filled f-levels. The carrier concentration is reduced upon substituting RE3+for Yb2+, adding one electron to the system and improving thezTvalues 30–40% over that of the pristine material.


2014 ◽  
Vol 70 (6) ◽  
pp. 533-535 ◽  
Author(s):  
Jan Fábry ◽  
Lubomír Havlák ◽  
Monika Kučeráková ◽  
Michal Dušek

The title structures NaGdS2(sodium gadolinium sulfide), NaLuS2(sodium lutetium sulfide) and NaYS2(sodium yttrium sulfide) were redetermined in order to improve the structural information available for the family of group 1 and thallium rare earth sulfides, which are isostructural with the rhombohedral α-NaFeO2structure type. In particular, the present investigation has been directed at the rhombohedral sodium rare earth sulfides. The observed dependence of the fractional coordinatez(S2−) on the identity of the rare earth element in the newly determined structures is in agreement with the known structures of the potassium and rubidium analogues. Crystals of NaGdS2and NaLuS2display obverse–reverse twinning.


2011 ◽  
Vol 471 (3-4) ◽  
pp. 66-70 ◽  
Author(s):  
M.R. Koblischka ◽  
A. Koblischka-Veneva ◽  
M. Muralidhar ◽  
Th. Wolf ◽  
N. Hari Babu ◽  
...  

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