Diamond ascent by rift-driven disruption of cratonic mantle keels

Diamonds are erupted at Earth’s surface in volatile-rich magmas called kimberlites1,2,3. These enigmatic magmas, originating from depths exceeding 150 kilometres in Earth’s mantle1, occur in stable cratons and in pulses broadly synchronous with supercontinent cyclicity4. Whether their mobilization is driven by mantle plumes5 or mechanical weakening of cratonic lithosphere4,6 remains unclear. Here we show that most kimberlites spanning the past billion years erupted approximately 25 million years after the onset of continental fragmentation, suggesting an association with rifting processes. Our dynamic models show that physically steep lithosphere-asthenosphere boundaries formed during terminal rifting (necking) generate convective instabilities in the asthenosphere that slowly migrate many hundreds of kilometres inboard of the rift, causing destabilization of cratonic mantle keel tens of kilometres thick. Displaced lithosphere is replaced by hot, upwelling asthenosphere in the return flow, causing partial melting of carbonated mantle and variable assimilation of lithospheric material. The resulting small-volume kimberlite magmas ascend rapidly and adiabatically, exsolving amounts of carbon dioxide (CO2) that are consistent with independent constraints7. Our model reconciles diagnostic kimberlite features including association with cratons and geochemical characteristics that implicate a common asthenospheric mantle source contaminated by cratonic lithosphere8. Together, these results provide a quantitative and mechanistic link between kimberlite episodicity and supercontinent cycles via progressive disruption of cratonic keels.

Gravity constraints on structure of the East-West Antarctic lithospheric transition zone

<p><b>The differing structural evolution of cratonic East Antarctica and younger West Antarctica has resulted in contrasting lithospheric and asthenospheric mantle viscosities between the two regions. Combined with poor constraints on the upper mantle viscosity structure of the continent, estimates of surface uplift in Antarctica predicted from models of glacial isostatic adjustment (GIA) and observed by Global Satellite Navigation System (GNSS) contain large misfits. This thesis presents a gravity study ofthe lithospheric transition zone beneath the Taylor Valley, Antarctica, conducted to constrain the variation in lithological parameters such as viscosity and density of the upper mantle across this region.</b></p> <p>During this study 119 new gravity observations were collected in the ice-free regions of the Taylor Valley and amalgamated with 154 existing land-based gravity observations, analysed alongside aerogravity measurements of southern Victoria Land. Gravity data are used to construct 2D gravity models of the subsurface beneath this region. An eastward gradient in Bouguer anomalies of ~- 1.6 mGal/km is observed within the Taylor Valley. Models reveal thickening of the Moho from 23±5 km beneath the Ross Sea to 35±5 km in the Polar Plateau (dipping at 24.5±7.2°), and lithospheric mantle 100 km thicker in East Antarctica (~200±30 km) than West Antarctica (~90±30 km). </p> <p>Models of predicted surface uplift history are used to estimate an asthenospheric mantle viscosity of 2.1x1020 Pa.s at full surface recovery beneath the Ross Embayment, differing by ~14% from the viscosity at 50% recovery. The temperature contrast between lithospheric and asthenospheric mantle is estimated as ~400°C, equivalent to a viscosity that decreases by a factor of about 30 over the mantle boundary.</p> <p>Results demonstrate that the history of surface uplift in the study area may be complicated, resulting in observations of uplift, or subsidence, at GNSS stations. Future work should incorporate additional geophysical methods, such as seismicity and electrical resistivity, improving constraints on gravity models. A better understanding of the surface uplift (or subsidence) history in the Transantarctic Mountains is critical, with implications in reducing uncertainty in GIA models.</p>

Gravity constraints on structure of the East-West Antarctic lithospheric transition zone

<p><b>The differing structural evolution of cratonic East Antarctica and younger West Antarctica has resulted in contrasting lithospheric and asthenospheric mantle viscosities between the two regions. Combined with poor constraints on the upper mantle viscosity structure of the continent, estimates of surface uplift in Antarctica predicted from models of glacial isostatic adjustment (GIA) and observed by Global Satellite Navigation System (GNSS) contain large misfits. This thesis presents a gravity study ofthe lithospheric transition zone beneath the Taylor Valley, Antarctica, conducted to constrain the variation in lithological parameters such as viscosity and density of the upper mantle across this region.</b></p> <p>During this study 119 new gravity observations were collected in the ice-free regions of the Taylor Valley and amalgamated with 154 existing land-based gravity observations, analysed alongside aerogravity measurements of southern Victoria Land. Gravity data are used to construct 2D gravity models of the subsurface beneath this region. An eastward gradient in Bouguer anomalies of ~- 1.6 mGal/km is observed within the Taylor Valley. Models reveal thickening of the Moho from 23±5 km beneath the Ross Sea to 35±5 km in the Polar Plateau (dipping at 24.5±7.2°), and lithospheric mantle 100 km thicker in East Antarctica (~200±30 km) than West Antarctica (~90±30 km). </p> <p>Models of predicted surface uplift history are used to estimate an asthenospheric mantle viscosity of 2.1x1020 Pa.s at full surface recovery beneath the Ross Embayment, differing by ~14% from the viscosity at 50% recovery. The temperature contrast between lithospheric and asthenospheric mantle is estimated as ~400°C, equivalent to a viscosity that decreases by a factor of about 30 over the mantle boundary.</p> <p>Results demonstrate that the history of surface uplift in the study area may be complicated, resulting in observations of uplift, or subsidence, at GNSS stations. Future work should incorporate additional geophysical methods, such as seismicity and electrical resistivity, improving constraints on gravity models. A better understanding of the surface uplift (or subsidence) history in the Transantarctic Mountains is critical, with implications in reducing uncertainty in GIA models.</p>

Phanerozoic record of mantle-dominated arc magmatic surges in the Zealandia Cordillera

We integrated new and existing bedrock and detrital zircon dates from the Zealandia Cordillera to explore the tempo of Phanerozoic arc magmatism along the paleo-Pacific margin of southeast Gondwana. We found that episodic magmatism was dominated by two high-magma-addition-rate (MAR) events spaced ~250 m.y. apart in the Devonian (370–368 Ma) and the Early Cretaceous (129–105 Ma). The intervening interval between high-MAR events was characterized by prolonged, low-MAR activity in a geographically stable location for more than 100 m.y. We found that the two high-MAR events in Zealandia have distinct chemistries (S-type for the Devonian and I-type for the Cretaceous) and are unlikely to have been related by a repeating, cyclical process. Like other well-studied arc systems worldwide, the Zealandia Cordillera high-MAR events were associated with upper-plate deformation; however, the magmatic events were triggered by enhanced asthenospheric mantle melting in two distinct arc-tectonic settings—a retreating slab and an advancing slab, respectively. Our results demonstrate that dynamic changes in the subducting slab were primary controls in triggering mantle flare-up events in the Phanerozoic Zealandia Cordillera.

Oxidized sulfur-rich arc magmas formed porphyry Cu deposits by 1.88 Ga

Most known porphyry Cu deposits formed in the Phanerozoic and are exclusively associated with moderately oxidized, sulfur-rich, hydrous arc-related magmas derived from partial melting of the asthenospheric mantle metasomatized by slab-derived fluids. Yet, whether similar metallogenic processes also operated in the Precambrian remains obscure. Here we address the issue by investigating the origin, fO2, and S contents of calc-alkaline plutonic rocks associated with the Haib porphyry Cu deposit in the Paleoproterozoic Richtersveld Magmatic Arc (southern Namibia), an interpreted mature island-arc setting. We show that the ca. 1886–1881 Ma ore-forming magmas, originated from a mantle-dominated source with minor crustal contributions, were relatively oxidized (1‒2 log units above the fayalite-magnetite-quartz redox buffer) and sulfur-rich. These results indicate that moderately oxidized, sulfur-rich arc magma associated with porphyry Cu mineralization already existed in the late Paleoproterozoic, probably as a result of recycling of sulfate-rich seawater or sediments from the subducted oceanic lithosphere at that time.

Early Cretaceous crust–mantle interaction linked to rollback of the Palaeo-Pacific flat-subducting slab: constraints from the intermediate–felsic volcanic rocks of the northern Great Xing’an Range, NE China

Late Mesozoic igneous rocks are important for deciphering the Mesozoic tectonic setting of NE China. In this paper, we present whole-rock geochemical data, zircon U–Pb ages and Lu–Hf isotope data for Early Cretaceous volcanic rocks from the Tulihe area of the northern Great Xing’an Range (GXR), with the aim of evaluating the petrogenesis and genetic relationships of these rocks, inferring crust–mantle interactions and better constraining extension-related geodynamic processes in the GXR. Zircon U–Pb ages indicate that the rhyolites and trachytic volcanic rocks formed during late Early Cretaceous time (c. 130–126 Ma). Geochemically, the highly fractionated I-type rhyolites exhibit high-K calc-alkaline, metaluminous to weakly peraluminous characteristics. They are enriched in light rare earth elements (LREEs) and large-ion lithophile elements (LILEs) but depleted in high-field-strength elements (HFSEs), with their magmatic zircons ϵHf(t) values ranging from +4.1 to +9.0. These features suggest that the rhyolites were derived from the partial melting of a dominantly juvenile, K-rich basaltic lower crust. The trachytic volcanic rocks are high-K calc-alkaline series and exhibit metaluminous characteristics. They have a wide range of zircon ϵHf(t) values (−17.8 to +12.9), indicating that these trachytic volcanic rocks originated from a dominantly lithospheric-mantle source with the involvement of asthenospheric mantle materials, and subsequently underwent extensive assimilation and fractional crystallization processes. Combining our results and the spatiotemporal migration of the late Early Cretaceous magmatic events, we propose that intense Early Cretaceous crust–mantle interaction took place within the northern GXR, and possibly the whole of NE China, and that it was related to the upwelling of asthenospheric mantle induced by rollback of the Palaeo-Pacific flat-subducting slab.

Petrolgy of the volcanic/subvolcanic members of the volcano-sedimentary Maden Complex in Eastern Turkey

&lt;p&gt;Maden Complex exposed in Eastern Turkey, is a succession of volcano-sedimentary rocks and tectonically overlain by Bitlis Metamorphics and Cretaceous ophiolitic rocks. The succession includes shallow-water deposits and deep marine pelagic sediments intercalated with pillow lavas ranging from a few centimeters to ten meters in diameter. The planktonic foraminiferal assemblages from micritic limestones and zircon U-Pb ages from selected sedimentary rocks indicate the age of Late Ypresian - Early Lutetian. Plagioclase and &amp;#160;clinopyroxenes are the main mineral phases, olivine rarely found as altered phenocrysts. Clinopyroxenes are augite and diopside, and their compositions are ranging between Wo&lt;sub&gt;44-51&lt;/sub&gt;, En&lt;sub&gt;27-43&lt;/sub&gt;, Fe&lt;sub&gt;10-21&lt;/sub&gt;. The anorthite contents of plagioclases are between 32- 67 % in unaltered grains. The crystallization temperatures and pressures obtained from clinopyroxene chemistry are ranging from 1126 to 1250&lt;sup&gt;o&lt;/sup&gt;C and 3 to 8 Kbar, respectively. The majority of the volcanic/subvolcanic rocks are subalkaline-tholeiitic basalts however; a few andesitic and rhyolitic derivatives are also present. The whole &amp;#8211; rock and&amp;#160; Sr-Nd-Pb isotope compositions reveal that the&amp;#160; basaltic rocks are originated from E-MORB like asthenospheric mantle source without a subduction component.&lt;/p&gt;

Petrogenesis and Geodynamic Implications of a Newly Discovered Basanite Dike in Zaolin, Jingdezhen City, South China

A recently discovered basanite dike in the Zaolin area of Jingdezhen, South China, contains mantle xenocrysts such as kink-banded olivines, olivines + orthopyroxenes assemblage, and chromites. In addition, polymorphic carbonates of the MgCO3–FeCO3 series occur as augens, either independently or interspersed with diopside and spinel in the matrix. The rock is characterized by high Cr and Ni contents, high whole-rock Mg# values (0.66–0.72), and high Ca/Al (0.72–1.03) and TFeO/MgO (1.1–1.3) ratios and is alkali-rich with Na2O &gt; K2O. The trace-element partition patterns are similar to those of other basanites in eastern China as well as ocean island basalts. Whole-rock geochemical analyses show depleted Sr and Nd isotopic compositions (86Sr/87Sr=0.70358–0.703853, εNd=2.52–6.73). These data indicate that the rock has experienced negligible crustal contamination, should be derived from asthenospheric mantle, or mixed by the MORB with EMI/EMII mantle and have been carbonated. The calculated T–P conditions of the melt in equilibrium with xeno-olivine are 1160–1320°C at the mantle depth. The high Cr# values of the spinel xenocrysts indicate that the lithospheric mantle under the Jingdezhen area was probably relict Proterozoic mantle. The Ar–Ar plateau age and the isochron and inverse isochron ages for the matrix of the basanite are all 44 Ma. The basanite, as well as other alkaline basalt or lamprophyre dikes in southeastern China, formed in a rifting regime during the Eocene.

Bimodal magmatism produced by delamination: geochemical evidence from late Palaeozoic volcanic rocks from the Yili Block, Western Tianshan, Northwestern China

The Western Tianshan orogenic belt is essential for understanding the evolution of the Central Asian orogenic belt. However, no agreement exists among geologists about its tectonic environment during the Late Palaeozoic. The volcanic rocks of the Yishijilike and Wulang Formation in the Yili Block, Western Tianshan, formed in the Late Carboniferous to Early Permian, mainly consist of a bimodal suite of basalts – basaltic andesites and rhyolites, with only some intermediate rocks. Mafic rocks are slightly enriched in light rare earth elements (LREE) and depleted in Nb, Ta, Zr and Hf, suggesting a subduction-modified depleted mantle source. Some mafic samples in the Early Permian bimodal volcanic rocks have high Ti contents with relatively high concentrations of Nb and high field strength elements (HFSE) and low contents of heavy rare earth elements (HREE). These rocks are similar to the continental flood basalts, which suggests that they formed from an asthenospheric mantle. This paper indicates that mafic members were created by the partial melting of the asthenospheric mantle material and subduction-modified lithospheric mantle mixture. Some rhyolites and dacites in the Wulang formation were enriched in Ga, Nb, Zr, Ce and Y and depleted in Sr and Eu. Additionally, they showed fractionation of rare earth elements (REE) with negative Eu anomalies, which is indicative of an A-type affinity of felsic rocks. The genesis of mafic members and an A-type affinity of felsic members indicate that the Late Carboniferous – Early Permian magmatism in the Western Tianshan area formed as a result of an extensional setting. This study also reveals bimodal magmatism produced by delamination in an extensional tectonic setting.

Supplemental Material: Transition from the lithospheric to asthenospheric mantle-derived magmatism in the Early Jurassic along eastern Bangong–Nujiang Suture, Tibet: Evidence for continental arc extension induced by slab rollback

Table S1: Zircon LA-ICP-MS U-Pb data of the early Jurassic mafic rocks from the Kaqiong microblock; Table S2: Zircon LA-ICP-MS REE (ppm) data of the early Jurassic mafic rocks from the Kaqiong microblock; Table S3: Whole-rock major (%) and trace (ppm) element data of the early Jurassic mafic rocks from the Kaqiong microblock; Table S4: Zircon LA-MC-ICP-MS Lu-Hf data of the early Jurassic mafic rocks from the Kaqiong microblock; Table S5: Whole-rock Sr-Nd isotopic data of the early Jurassic mafic rocks from the Kaqiong microblock.