Mean-field study of the synergic effect of the CO–NO reaction on a heterogeneous substrate of interconnected sectors
Keyword(s):
A mean-field theory study is made of the behaviour of a kinetic model of the reduction reaction of NO by CO catalyzed by a surface with simple heterogeneity consisting of two interconnected sectors that differ in their NO dissociation activation energy. A synergistic effect is manifested in the activity, apparent activation energy, and reaction order of the system. This situation, analogous to that observed in the literature in the case of a heterogeneous catalytic particle, is used in the paper to analyze a real case of a bimetallic catalyst.
1980 ◽
Vol 41
(C6)
◽
pp. C6-97-C6-100
◽
Keyword(s):
2010 ◽
Vol 200
(1)
◽
pp. 012158
◽
Keyword(s):