ELECTRODE POTENTIALS OF THORIUM TETRACHLORIDE IN ALKALI CHLORIDE MELTS

1964 ◽  
Vol 42 (6) ◽  
pp. 1315-1322 ◽  
Author(s):  
R. Srinivasan ◽  
S. N. Flengas
Keyword(s):  
Silver Chloride ◽  
Gravimetric Method ◽  
Reference Electrode ◽  
The Other ◽  
Alkali Chloride ◽  
Electrode Potentials ◽  
Silver Chloride Reference Electrode ◽  
Chloride Melts ◽  
Silver Silver ◽  
Silver Silver Chloride

The electrode potentials of the system Th, ThCl4 (KCl, NaCl) were measured at various concentrations of thorium chloride, and at temperatures between 670 °C and 850 °C, using a silver – silver chloride reference electrode. It was shown by a direct gravimetric method that the reaction,Th(metal) + ThCl4(melt) = 2ThCl2(in melt),postulated by previous investigators, did not take place.The activity coefficients, and the other partial molal properties of the solutions of ThCl4, in the equimolar mixture of potassium and sodium chlorides, were calculated as a function of temperature from the e.m.f. measurements.

ELECTRODE POTENTIALS OF THE URANIUM CHLORIDES IN FUSED ALKALI CHLORIDE SOLUTIONS

1961 ◽  
Vol 39 (4) ◽  
pp. 773-784 ◽  
Author(s):  
S. N. Flengas
Keyword(s):  
Activity Coefficients ◽  
Electrode Potential ◽  
Silver Chloride ◽  
Reference Electrode ◽  
Redox Potentials ◽  
Alkali Chloride ◽  
Electrode Potentials ◽  
Silver Chloride Reference Electrode ◽  
Silver Silver ◽  
Silver Silver Chloride

Using a silver – silver chloride reference electrode, the electrode potentials of the system U, UCl3(KCl, NaCl) and the redox potentials of the system Pt, UCl3, UCl4(KCl, NaCl) were measured at various concentrations of the uranium chlorides and at temperatures between 650 and 850 °C.From the results, the electrode potential of the system U, UCl4(KCl, NaCl) was calculated. In addition, the activity coefficients and partial molal properties of dilute solutions of UCl3 and UCl4 in the equimolar mixture of potassium and sodium chlorides were calculated.

The preparation in situ of a silver-silver chloride reference electrode

1994 ◽  
Vol 6 (11-12) ◽  
pp. 945-952 ◽  
Author(s):  
Juozas Kulys ◽  
Jens A Munk ◽  
Thomas Buch-Rasmussen ◽  
Henrik E. Hansen
Keyword(s):  
Silver Chloride ◽  
Reference Electrode ◽  
Silver Chloride Reference Electrode ◽  
Silver Silver ◽  
Silver Silver Chloride

VOLTAIC CELLS IN FUSED SALTS: PART II. THE SYSTEMS: (a) SILVER – SILVER CHLORIDE, LEAD – LEAD CHLORIDE; (b) SILVER – SILVER CHLORIDE, ZINC – ZINC CHLORIDE; AND (c) SILVER – SILVER CHLORIDE, NICKEL – NICKELOUS CHLORIDE

1957 ◽  
Vol 35 (11) ◽  
pp. 1254-1259 ◽  
Author(s):  
S. N. Flengas ◽  
T. R. Ingraham
Keyword(s):  
Zinc Chloride ◽  
Dissociation Constants ◽  
Silver Chloride ◽  
Reference Electrode ◽  
Lead Chloride ◽  
Effect Of Temperature ◽  
Fused Salts ◽  
Electrode Potentials ◽  
Silver Silver ◽  
Silver Silver Chloride

Using a reversible silver – silver chloride reference electrode, described in the first paper of this series, standard electrode potentials have been established for the systems lead – lead chloride, zinc – zinc chloride, and nickel – nickelous chloride, in melts containing equimolar quantities of KCl and NaCl. Deviations from ideality were observed, and these were attributed to the formation of complexes. Dissociation constants for the complexes were calculated. The effect of temperature on the electromotive forces of the voltaic cells was also measured, and the heats of the cell reactions were calculated from the data.

Collaborative Study on a Potentiometric Titration of Soluble Chlorides in Feeds

1969 ◽  
Vol 52 (3) ◽  
pp. 607-609
Author(s):  
D L Sharpe
Keyword(s):  
Nitric Acid ◽  
Silver Chloride ◽  
Collaborative Study ◽  
Reference Electrode ◽  
Arithmetic Mean ◽  
Official Method ◽  
Silver Chloride Reference Electrode ◽  
Coefficients Of Variations ◽  
Silver Silver ◽  
Silver Silver Chloride

Abstract In the method described, a weighed feed sample is placed in 200 ml water, 1 ml nitric acid is added, and the chlorides present are titrated with silver nitrate. The titration is performed with a potentiometer equipped with a silver-silver chloride reference electrode a nd a silver indicating electrode. Collaborative s tudy showed that the method is more precise than the official method. An arithmetic mean for the coefficients of variations was 8.0 and 4.1, respectively, for the official and the potentiometric method.

Fundamental Data Acquisition toward Silver-Silver Chloride Reference Electrode

2019 ◽  
Vol 166 (6) ◽  
pp. E159-E164 ◽  
Author(s):  
Dalsung Yoon ◽  
Adam Baggett ◽  
Supathorn Phongikaroon ◽  
James A. King ◽  
Ken Marsden
Keyword(s):  
Data Acquisition ◽  
Silver Chloride ◽  
Reference Electrode ◽  
Silver Chloride Reference Electrode ◽  
Silver Silver ◽  
Silver Silver Chloride

An agar-based silver|silver chloride reference electrode for use in micro-electrochemistry

1999 ◽  
Vol 1 (5) ◽  
pp. 180-183 ◽  
Author(s):  
Achim Walter Hassel ◽  
Koji Fushimi ◽  
Masahiro Seo
Keyword(s):  
Silver Chloride ◽  
Reference Electrode ◽  
Silver Chloride Reference Electrode ◽  
Silver Silver ◽  
Silver Silver Chloride

Construction and Calibration of an Internal Silver/Silver Chloride Reference Electrode for Supercritical Fluid Studies

CORROSION ◽  
1991 ◽  
Vol 47 (3) ◽  
pp. 185-188 ◽  
Author(s):  
S. Huang ◽  
K. Daehling ◽  
T. E. Carleson ◽  
A. Propp
Keyword(s):  
Supercritical Fluid ◽  
Silver Chloride ◽  
Reference Electrode ◽  
Silver Chloride Reference Electrode ◽  
Silver Silver ◽  
Silver Silver Chloride

scholarly journals Needle-Type Ultra Micro Silver/Silver Chloride Reference Electrode for Use in Micro-Electrochemistry

2005 ◽  
Vol 21 (8) ◽  
pp. 907-912 ◽  
Author(s):  
Tatsuya KITADE ◽  
Keisuke KITAMURA ◽  
Shigehiko TAKEGAMI ◽  
Yoko MIYATA ◽  
Miwa NAGATOMO ◽  
...  
Keyword(s):  
Silver Chloride ◽  
Reference Electrode ◽  
Needle Type ◽  
Silver Chloride Reference Electrode ◽  
Silver Silver ◽  
Silver Silver Chloride
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