A Silver-Silver Chloride Reference Electrode for the High Temperature and High Pressure Electrochemistry

CORROSION ◽  
1977 ◽  
Vol 33 (11) ◽  
pp. 418-420 ◽  
Author(s):  
A. K. AGRAWAL ◽  
R. W. STAEHLE
CORROSION ◽  
1976 ◽  
Vol 32 (9) ◽  
pp. 374-377 ◽  
Author(s):  
I. J. MAGAR ◽  
P. E. MORRIS

Abstract A step-by-step procedure is described for constructing a single compartment, PTFE-contained silver/silver chloride reference electrode. Representative electrochemical measurements have shown that this reference electrode functions accurately at temperatures up to 316 C and test periods greater than two months.


1964 ◽  
Vol 42 (6) ◽  
pp. 1315-1322 ◽  
Author(s):  
R. Srinivasan ◽  
S. N. Flengas

The electrode potentials of the system Th, ThCl4 (KCl, NaCl) were measured at various concentrations of thorium chloride, and at temperatures between 670 °C and 850 °C, using a silver – silver chloride reference electrode. It was shown by a direct gravimetric method that the reaction,Th(metal) + ThCl4(melt) = 2ThCl2(in melt),postulated by previous investigators, did not take place.The activity coefficients, and the other partial molal properties of the solutions of ThCl4, in the equimolar mixture of potassium and sodium chlorides, were calculated as a function of temperature from the e.m.f. measurements.


1994 ◽  
Vol 6 (11-12) ◽  
pp. 945-952 ◽  
Author(s):  
Juozas Kulys ◽  
Jens A Munk ◽  
Thomas Buch-Rasmussen ◽  
Henrik E. Hansen

1969 ◽  
Vol 52 (3) ◽  
pp. 607-609
Author(s):  
D L Sharpe

Abstract In the method described, a weighed feed sample is placed in 200 ml water, 1 ml nitric acid is added, and the chlorides present are titrated with silver nitrate. The titration is performed with a potentiometer equipped with a silver-silver chloride reference electrode a nd a silver indicating electrode. Collaborative s tudy showed that the method is more precise than the official method. An arithmetic mean for the coefficients of variations was 8.0 and 4.1, respectively, for the official and the potentiometric method.


2019 ◽  
Vol 166 (6) ◽  
pp. E159-E164 ◽  
Author(s):  
Dalsung Yoon ◽  
Adam Baggett ◽  
Supathorn Phongikaroon ◽  
James A. King ◽  
Ken Marsden

2005 ◽  
Vol 21 (8) ◽  
pp. 907-912 ◽  
Author(s):  
Tatsuya KITADE ◽  
Keisuke KITAMURA ◽  
Shigehiko TAKEGAMI ◽  
Yoko MIYATA ◽  
Miwa NAGATOMO ◽  
...  

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