Electron spin resonance study of the interaction of tert-butyl hydroperoxide with zinc oxide

1968 ◽  
Vol 46 (13) ◽  
pp. 2329-2331 ◽  
Author(s):  
Maurice Codell ◽  
Henry Gisser ◽  
R. D. Iyengar
Keyword(s):  
Electron Spin Resonance ◽  
Electron Spin ◽  
Oxygen Vacancies ◽  
Electron Spin Resonance Study ◽  
Resonance Signal ◽  
Tertiary Butyl ◽  
Butyl Hydroperoxide ◽  
Tert Butyl Hydroperoxide ◽  
Spin Resonance ◽  
Spin Resonance Study

The complexity of the electron spin resonance signal, appearing at g = 1.96 on ZnO vacuum outgassed at higher temperatures, has been examined by adsorption of tertiary butyl hydroperoxide (TBHP). Two individual signals with g values 1.961 and 1.965 observed following TBHP adsorption have been attributed to Zn+ ions and oxygen vacancies with trapped electrons.

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