A Comparative Study of Bu4NBr, NaBPh4, Ph4PCl, and Ph4AsCl in Water and Methanol at 25 °C: Partial Molal Volumes, Heat Capacities, and Viscosities

1972 ◽  
Vol 50 (19) ◽  
pp. 3167-3178 ◽  
Author(s):  
C. Jolicoeur ◽  
P. R. Philip ◽  
G. Perron ◽  
P. A. Leduc ◽  
J. E. Desnoyers
Keyword(s):  
Comparative Study ◽  
Transfer Functions ◽  
Heat Capacities ◽  
Solvent Interactions ◽  
Apparent Molal Volumes ◽  
Partial Molal Volumes ◽  
Molal Volumes

The apparent molal volumes [Formula: see text] and heat capacities [Formula: see text] of Bu4NBr, NaBPh4, Ph4PCl, and Ph4AsCl have been measured in water and methanol at 25 °C in the concentration range 0.01–0.2 M. The viscosity of aqueous NaBPh4 and Ph4AsCl have also been measured at 25 °C and in the same concentration range. Individual ionic values have been estimated for most of these properties. A comparison of these values for the quaternary ions BU4N+, [Formula: see text], Ph4P+, Ph4As+ illustrates sizable differences in the solute–solvent interactions of alkyl and aryl substituted ions. Some specificity is also suggested in the solvation of the tetraphenyl ions, as shown by a comparison of the properties which should reflect directly the size of the ions [Formula: see text]and also in (H2O → CH3OH) transfer functions.

Volumes and Heat Capacities of Cyclic Ethers and Amines in Water and of some Electrolytes in these Mixed Aqueous Solvents

1975 ◽  
Vol 53 (17) ◽  
pp. 2591-2597 ◽  
Author(s):  
Osamu Klyohara ◽  
Gérald Perron ◽  
Jacques E. Desnoyers
Keyword(s):  
Mixed Solvent ◽  
Transfer Functions ◽  
Heat Capacities ◽  
Cyclic Ethers ◽  
Apparent Molal Volumes ◽  
Cyclic Amines ◽  
Specific Heats ◽  
Molal Volumes ◽  
Mixed Aqueous Solvents ◽  
Structural Influence

The densities and volumetric specific heats of p-dioxane, tetrahydropyran, morpholine, piperidine, and piperazine were measured in water at 25 °C with a flow densimeter and a flow microcalorimeter. The same properties were also determined for LiCl, NaCl, Me4NBr, and Bu4NBr at 0.1 m in dioxane–water, morpholine–water, and piperidine–water mixtures. The derived apparent molal volumes and heat capacities of the nonelectrolytes in water and the transfer functions of the electrolytes from water to the mixed solvent suggest that all the present cyclic amines and ethers are hydrophobic; the overall structural influence is very small with dioxane and large with piperidine.

Volumes and Heat Capacities of Transfer of Tetraalkylammonium Bromides from Water to Aqueous Urea Solutions at 25 °C

1973 ◽  
Vol 51 (2) ◽  
pp. 187-191 ◽  
Author(s):  
P. R. Philip ◽  
J. E. Desnoyers ◽  
A. Hade
Keyword(s):  
Transfer Functions ◽  
Pure Water ◽  
Heat Capacities ◽  
Tetraalkylammonium Bromides ◽  
Apparent Molal Volumes ◽  
Aqueous Urea ◽  
Molal Volumes

The apparent molal volumes and heat capacities of tetraalkylammonium bromides were measured in urea–water mixtures at 25 °C. The volumes and heat capacities of transfer from water to urea-water mixtures indicate that structural hydration effects are smaller in urea–water mixtures than in water. Also a comparison with the corresponding transfer functions from H2O to D2O suggests that urea–water mixtures are less structured than pure water.

Apparent Molal Volumes and Heat Capacities of Tetrabutylammonium Bromide in Aqueous Electrolyte Solutions

1975 ◽  
Vol 53 (21) ◽  
pp. 3206-3210 ◽  
Author(s):  
Nicole Desrosiers ◽  
Jacques E. Desnoyers
Keyword(s):  
Aqueous Solutions ◽  
Long Range ◽  
Transfer Functions ◽  
Aqueous Electrolyte ◽  
Tetrabutylammonium Bromide ◽  
Electrolyte Solutions ◽  
Heat Capacities ◽  
Apparent Molal Volumes ◽  
Flow Microcalorimeter ◽  
Molal Volumes

The apparent molal volumes and heat capacities of Bu4NBr were measured in aqueous solutions of NaF, NaCl, NaBr, KBr, NaAc, and NH4Ac at 25 °C with a flow densimeter and a flow microcalorimeter. The derived transfer functions of Bu4NBr from water to the electrolyte solutions, after correction for the long-range coulombic forces, are all negative. This suggests that the noncoulombic interactions between hydrophobic and hydrophilic ions result in negative contributions to volumes and heat capacities.

Apparent molal heat capacities and volumes of aqueous electrolytes at 25 °C: NaClO3, NaClO4, NaNO3, NaBrO3, NaIO3, KClO3, KBrO3, KIO3, NH4NO3, NH4Cl, and NH4ClO4

1978 ◽  
Vol 56 (1) ◽  
pp. 24-28 ◽  
Author(s):  
Alain Roux ◽  
Goolam M. Musbally ◽  
Gérald Perron ◽  
Jacques E. Desnoyers ◽  
Prem Paul Singh ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Infinite Dilution ◽  
Heat Capacities ◽  
Aqueous Electrolytes ◽  
Apparent Molal Volumes ◽  
Hückel Theory ◽  
Standard Values ◽  
Molal Volumes ◽  
Apparent Molal Heat Capacities

Measurements at 25 °C with flow calorimeters and densimeters have led to heat capacities and densities of aqueous solutions of 11 1:1 electrolytes: NaClO3, NaBrO3, NaIO3, NaNO3, NaClO4, NH4NO3, KClO3, KBrO3, KIO3, NH4Cl, and NH4ClO4. The first 6 salts were studied up to near saturation. We have used results of these measurements to obtain apparent molal heat capacities and apparent molal volumes of the various solutes. Extrapolation to infinite dilution on the basis of the Debye–Hückel theory bas led to [Formula: see text]and [Formula: see text] values for each solute. We have compared these standard values with results of earlier investigations.

Volumes and heat capacities of some amino acids in water at 25 °C

1977 ◽  
Vol 55 (19) ◽  
pp. 3364-3367 ◽  
Author(s):  
JagDish C. Ahluwalia ◽  
Claude Ostiguy ◽  
Gerald Perron ◽  
Jacques E. Desnoyers
Keyword(s):  
Amino Acids ◽  
Heat Capacities ◽  
Apparent Molal Volumes ◽  
Flow Microcalorimeter ◽  
Ionic Groups ◽  
The Poor ◽  
Molal Volumes

The apparent molal volumes and heat capacities of nine amino acids were measured in water at 25 °C with a flow densimeter and a flow microcalorimeter. It is shown that the poor additivity of the standard partial molal quantities of amino acids in water are attributable to the ionization of the two groups NH2 and COOH. The hydration of these ionic groups interfere with each other when they are separated by less than three carbon atoms.

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