Novel peroxosolvates of tetraalkylammonium halides: the first case of layers containing hydrogen-bonded peroxide molecules

Novel peroxosolvates of tetraalkylammonium halides Et4N+Cl–•2(H2O2) (1), Et4N+Br–•2(H2O2) (2), Me3(ClCH2CH2)N+Cl–•H2O2 (3) and Me3PhN+Cl–•H2O2 (4) were prepared from concentrated hydrogen peroxide and the corresponding structures were determined by X-ray crystallography. Structures...

Green solvent assisted synthesis of cesium bismuth halide perovskite nanocrystals and the influences of slow and fast anion exchange rates

Halide perovskite nanocrystals of cesium bismuth iodide (Cs3Bi2I9) were prepared by a facile sonication-assisted method using a green solvent. The photoluminescence properties were tuned by anion exchange with tetraalkylammonium halides.

Supramolecular host–guest complexation of Lash's calix[4]azulene with tetraalkylammonium halides and tetrafluoroborate salts: binding and DFT computational studies

Calix[4]azulene1is shown to be an effective molecular receptor for tetraalkylammonium halide and BF4−salts.

Aqueous solutions of tetraalkylammonium halides: ion hydration, dynamics and ion–ion interactions in light of steric effects

The absence of hydrophobicity-driven cation aggregation is reported in TMABr and TBABr aqueous solutions, by means of microscopic simulations.