Effects of potassium ion on the electron-transfer reaction between Fe(CN)64− and TCNQ or chloranil
Keyword(s):
The effects of potassium ion on the electron-transfer reactions between Fe(CN)64− and 7,7,8,8-tetracyanoquinodimethane (TCNQ) or chloranil (QCl4) were studied with temperature-jump equipment; [Formula: see text]. The solvent was a 1:1 (v/v) mixture of acetonitrile–water. In both Systems, the forward rate constants (kr) were unaffected by the addition of KCl; kf(Fe(CN)64−/TCNQ) = (2.9 ± 0.2) × 106 M−1 s−1, and kr(Fe(CN)64−/QCl4) = (5.2 ± 0.4) × 104 M−1 s−1 On the other hand, the backward rate constants (kb) increased with the increase of the KCl concentration. The results are interpreted in terms of ion-pairing equilibria of Fe(CN)64− and Fe(CN)63−.
1966 ◽
Vol 88
(2)
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pp. 373-373
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Keyword(s):
2001 ◽
Vol 313
(1-2)
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pp. 37-42
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2011 ◽
Vol 440
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pp. 234-238
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1997 ◽
Vol 42
(23-24)
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pp. 3461-3470
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2006 ◽
Vol 422
(4-6)
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pp. 382-385
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