Article

J García; M J Comuñas; L Lugo; E R López; J Fernández

doi:10.1139/v99-014

Article

Canadian Journal of Chemistry ◽

10.1139/v99-014 ◽

1999 ◽

Vol 77 (3) ◽

pp. 299-307

Author(s):

J García ◽

M J Comuñas ◽

L Lugo ◽

E R López ◽

J Fernández

Keyword(s):

Experimental Data ◽

Infinite Dilution ◽

Excess Molar Volumes ◽

Excess Enthalpies ◽

Group Contributions ◽

Characteristic Parameters ◽

Molar Volumes ◽

Gibbs Energies ◽

Excess Gibbs Energies ◽

Group Contribution Model

Excess molar volumes at 298.15 K for the binary mixtures of a 1-bromoalkane with a n-alkane are reported. The VE values were obtained from measurements of the density with an Anton Paar densimeter. Literature data of excess Gibbs energies, excess enthalpies, excess volumes, and activity coefficients at infinite dilution for this kind of mixtures together with molar volumes and vaporization enthalpies of pure bromoalkanes were used to calculate the characteristic parameters of the Nitta-Chao group contribution model. With the obtained parameters, this model consistently describes the experimental data of the 1-bromoalkane + n-alkane mixtures. Furthermore, we have determined the energetic parameters for the Larsen version of the UNIFAC model.Key words: liquids, mixtures, thermodynamics, group contributions.

Excess Gibbs energies and excess molar volumes for binary mixtures: (2-pyrrolidone+water), (2-pyrrolidone+methanol), and (2-pyrrolidone+ethanol) at the temperature 313.15K

The Journal of Chemical Thermodynamics ◽

10.1016/s0021-9614(02)00231-8 ◽

2002 ◽

Vol 34 (10) ◽

pp. 1693-1701 ◽

Cited By ~ 14

Author(s):

Jan Zielkiewicz

Keyword(s):

Binary Mixtures ◽

Excess Molar Volumes ◽

Molar Volumes ◽

Gibbs Energies ◽

Excess Gibbs Energies

Thermodynamics of binary mixtures containing tertiary amines. II. Excess enthalpies of some N,N-dialkylmethylamine + benzene mixtures: Measurement and analysis in terms of group contributions, and estimation of excess Gibbs energies

Fluid Phase Equilibria ◽

10.1016/0378-3812(82)80020-4 ◽

1982 ◽

Vol 9 (3) ◽

pp. 213-223 ◽

Cited By ~ 9

Author(s):

Italo Ferino ◽

Bruno Marongiu ◽

Vincenzo Solinas ◽

Sergio Torrazza ◽

Henry V. Kehiaian

Keyword(s):

Binary Mixtures ◽

Excess Enthalpies ◽

Group Contributions ◽

Tertiary Amines ◽

Gibbs Energies ◽

Excess Gibbs Energies ◽

Measurement And Analysis

Thermodynamics of binary mixtures containing tertiary amines. I. Excess enthalpies of some N,N-dialkylmethylamine+normal alkane mixtures. Measurement and analysis in terms of group contributions. Estimation of excess gibbs energies

Fluid Phase Equilibria ◽

10.1016/0378-3812(82)85004-8 ◽

1982 ◽

Vol 9 (1) ◽

pp. 49-65 ◽

Cited By ~ 42

Author(s):

Italo Ferino ◽

Bruno Marongiu ◽

Vincenzo Solinas ◽

Sergio Torrazza ◽

Henry V. Kehiaian

Keyword(s):

Binary Mixtures ◽

Excess Enthalpies ◽

Group Contributions ◽

Tertiary Amines ◽

Normal Alkane ◽

Gibbs Energies ◽

Excess Gibbs Energies ◽

Measurement And Analysis

Thermodynamic properties of binary mixtures containing chloroalkanes. I. Analysis of the excess enthalpies and excess gibbs energies of 1-chloroalkane + + cyclohexane mixtures in terms of an extended quasichemical group contribution model (DISQUAC)

Fluid Phase Equilibria ◽

10.1016/0378-3812(86)87065-0 ◽

1986 ◽

Vol 27 ◽

pp. 445-456 ◽

Cited By ~ 15

Author(s):

Bruno Marongiu ◽

Henry V. Kehiaian

Keyword(s):

Thermodynamic Properties ◽

Binary Mixtures ◽

Group Contribution ◽

Excess Enthalpies ◽

Gibbs Energies ◽

Excess Gibbs Energies ◽

Group Contribution Model

Thermodynamic properties of binary mixtures containing aldehydes. III. Analysis of the excess enthalpies and excess Gibbs energies of n-alkanal + cyclohexane mixtures in terms of an extended quasichemical group contribution model (DISQUAC)

Fluid Phase Equilibria ◽

10.1016/0378-3812(85)87002-3 ◽

1985 ◽

Vol 21 (3) ◽

pp. 197-209 ◽

Cited By ~ 31

Author(s):

Henry V. Kehiaian ◽

Bruno Marongiu

Keyword(s):

Thermodynamic Properties ◽

Binary Mixtures ◽

Group Contribution ◽

Excess Enthalpies ◽

Gibbs Energies ◽

Excess Gibbs Energies ◽

Group Contribution Model

Thermodynamic properties of binary mixtures containing aldehydes. I. Excess enthalpies of some n-alkanal + n-alkane mixtures: Measurement and analysis in terms of a quasi-chemical group-contribution model and estimation of excess Gibbs Energies

Fluid Phase Equilibria ◽

10.1016/0378-3812(83)85016-x ◽

1983 ◽

Vol 12 (1-2) ◽

pp. 125-142 ◽

Cited By ~ 38

Author(s):

Italo Ferino ◽

Bruno Marongiu ◽

Vincenzo Solinas ◽

Sergio Torrazza ◽

Henry V. Kehiaian

Keyword(s):

Thermodynamic Properties ◽

Binary Mixtures ◽

Group Contribution ◽

Excess Enthalpies ◽

Gibbs Energies ◽

Excess Gibbs Energies ◽

Measurement And Analysis ◽

Group Contribution Model

Excess Molar Volumes and Excess Gibbs Energies inN-Methylformamide + Water, or + Methanol, or + Ethanol at the Temperature 303.15 K

Journal of Chemical & Engineering Data ◽

10.1021/je980001v ◽

1998 ◽

Vol 43 (4) ◽

pp. 650-652 ◽

Cited By ~ 30

Author(s):

Jan Zielkiewicz

Keyword(s):

Excess Molar Volumes ◽

Molar Volumes ◽

Gibbs Energies ◽

Excess Gibbs Energies

Excess molar volumes and viscosities of binary mixtures of some polyethers with propylamine at 298.15 K

Canadian Journal of Chemistry ◽

10.1139/v02-045 ◽

2002 ◽

Vol 80 (5) ◽

pp. 467-475 ◽

Cited By ~ 12

Author(s):

Amalendu Pal ◽

Rakesh Kumar Bhardwaj

Keyword(s):

Experimental Data ◽

Viscous Flow ◽

Binary Mixtures ◽

Entire Range ◽

Excess Volume ◽

Excess Molar Volumes ◽

Liquid Mixtures ◽

Molar Volumes ◽

Binary Liquid ◽

Volume Viscosity

Excess molar volumes (VmE) and dynamic viscosities (η) have been measured as a function of composition for binary liquid mixtures of propylamine with 2,5-dioxahexane, 2,5,8-trioxanonane, 2,5,8,11-tetraoxadodecane, 3,6,9-trioxaundecane, and 5,8,11-trioxapentadecane at 298.15 K. The excess volumes are positive over the entire range of composition for the systems propylamine + 2,5-dioxahexane, and + 3,6,9-trioxaundecane, negative for the systems propylamine + 2,5,8,11-tetraoxadodecane, and + 5,8,11-trioxapentadecane, and change sign from positive to negative for the remaining system propylamine + 2,5,8-trioxanonane. From the experimental data, deviations in the viscosity (Δln η) and excess energies of activation for viscous flow (ΔG*E) have been derived. These values are positive for all mixtures with the exception of propylamine + 2,5-dioxahexane.Key words : excess volume, viscosity, binary mixtures.

Excess Gibbs energies and excess enthalpies of liquid binary mixtures containing nitroalkanes

Fluid Phase Equilibria ◽

10.1016/0378-3812(93)85128-9 ◽

1993 ◽

Vol 84 ◽

pp. 281-296 ◽

Cited By ~ 6

Author(s):

Bruno Marongiu ◽

Roberto Monaci ◽

Silvia Porcedda

Keyword(s):

Binary Mixtures ◽

Excess Enthalpies ◽

Gibbs Energies ◽

Excess Gibbs Energies ◽

Liquid Binary Mixtures

Densities and Excess Molar Volumes of Binary and Ternary Mixtures Containing Acetonitrile + Acetophenone + 1,2-Pentanediol: Experimental Data, Correlation and Prediction by PFP Theory and ERAS Model

Journal of Solution Chemistry ◽

10.1007/s10953-010-9637-3 ◽

2011 ◽

Vol 40 (2) ◽

pp. 284-298 ◽

Cited By ~ 9

Author(s):

H. Iloukhani ◽

M. Almasi

Keyword(s):

Experimental Data ◽

Excess Molar Volumes ◽

Ternary Mixtures ◽

Data Correlation ◽

Pfp Theory ◽

Molar Volumes ◽

Binary And Ternary Mixtures ◽

Eras Model