Two-phase Model of Markov Processes for Particle Transport in Fluidized Bed Reactors

Author(s):  
Hui Gao ◽  
Yan Fu ◽  
Jimin Yuan ◽  
Jianping Li
2013 ◽  
Vol 19 (1) ◽  
pp. 13-24 ◽  
Author(s):  
Ahmad Shamiria ◽  
M.A. Hussaina ◽  
Farouq Mjallic ◽  
Navid Mostoufid

A comparative study describing gas-phase propylene polymerization in fluidized-bed reactors using Ziegler-Natta catalyst is presented. The reactor behavior was explained using a two-phase model (which is based on principles of fluidization) as well as simulation using the Aspen Polymers process simulator. The two-phase reactor model accounts for the emulsion and bubble phases which contain different portions of catalysts with the polymerization occurring in both phases. Both models predict production rate, molecular weight, polydispersity index (PDI) and melt flow index (MFI) of the polymer. We used both models to investigate the effect of important polymerization parameters, namely catalyst feed rate and hydrogen concentration, on the product polypropylene properties, such as production rate, molecular weight, PDI and MFI. Both the two-phase model and Aspen Polymers simulator showed good agreement in terms of production rate. However, the models differed in their predictions for weight-average molecular weight, PDI and MFI. Based on these results, we propose incorporating the missing hydrodynamic effects into Aspen Polymers to provide a more realistic understanding of the phenomena encountered in fluidized bed reactors for polyolefin production.


2015 ◽  
Vol 264 ◽  
pp. 706-719 ◽  
Author(s):  
Ahmad Shamiri ◽  
Suk Wei Wong ◽  
Mohd Fauzi Zanil ◽  
Mohamed Azlan Hussain ◽  
Navid Mostoufi

2019 ◽  
Vol 23 (Suppl. 5) ◽  
pp. 1413-1423
Author(s):  
Robbie Venderbosch ◽  
Wolter Prins ◽  
Swaaij van

The conversion rate of the mass transfer controlled oxidation of CO over a Pt/?-alumina catalyst (d = 65 ?m) has been studied in a fluidized bed (internal diameter = 0.05 m) p operated close to and in the turbulent fluid bed regime. The objectives were to investigate the gas-solids contacting efficiency to evaluate the conversion data in terms of overall mass transfer coefficients and define the apparent contact efficiency. At high superficial gas velocities, the concept of formation of particle agglomerates and voids is more realistic than the two-phase model considering discrete bubbles and a dense phase. The two-phase model is not useless but has hardly any relation with the real flow pattern in the turbulent regime.


Sign in / Sign up

Export Citation Format

Share Document