GRAIN-BOUNDARY SEGREGATION AND CO-SEGREGATION BEHAVIOR OF THREE ELEMENTS IN STEEL 2.25Gr1Mo

Author(s):  
WANG JUN ◽  
ER-BAO LIU ◽  
YU-DONG FU ◽  
QING-FEN LI
2012 ◽  
Vol 525-526 ◽  
pp. 273-276 ◽  
Author(s):  
Yu Dong Fu ◽  
Qing Fen Li ◽  
Wei Xin Sun

The present work is an effort to provide experimental results focusing on segregation behavior of phosphorus at grain boundary and the intergranular fracture behavio under low tensile stresses. AES (Auger electron spectroscopy) experiments and dynamic analyses on the non-equilibrium grain-boundary segregation (NGS) of phosphorus and the SEM photos of intergranular fracture in Auger specimens in 12Cr1MoV steel were carried out in this paper. The variation of phosphorus segregation level in grain boundary under different low tensile stresses and at different temperature were obtained. Results show that NGS of phosphorus occurred in the experimental steel while subjected to low tensile stresses. Maximum values of phosphorus segregation level were obtained at the critical times. SEM photos of intergranular fracture in Auger specimens of the test steel show that the intergranular fracture rate increased with increasing concentration of phosphorus. The intergranular fracture behavior is accordant with the segregation behavior of phosphorus at grain boundary.


2004 ◽  
Vol 83 (2) ◽  
pp. 344-352 ◽  
Author(s):  
Junghyun Cho ◽  
Jeffrey M. Rickman ◽  
Helen M. Chan ◽  
Martin P. Harmer

Author(s):  
C.L. Briant

Grain boundary segregation is the process by which solute elements in a material diffuse to the grain boundaries, become trapped there, and increase their local concentration at the boundary over that in the bulk. As a result of this process this local concentration of the segregant at the grain boundary can be many orders of magnitude greater than the bulk concentration of the segregant. The importance of this problem lies in the fact that grain boundary segregation can affect many material properties such as fracture, corrosion, and grain growth.One of the best ways to study grain boundary segregation is with Auger electron spectroscopy. This spectroscopy is an extremely surface sensitive technique. When it is used to study grain boundary segregation the sample must first be fractured intergranularly in the high vacuum spectrometer. This fracture surface is then the one that is analyzed. The development of scanning Auger spectrometers have allowed researchers to first image the fracture surface that is created and then to perform analyses on individual grain boundaries.


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