NON-INERTIAL ROTATIONAL DIFFUSION IN AXIALLY SYMMETRIC EXTERNAL POTENTIALS: APPLICATIONS TO ORIENTATIONAL RELAXATION OF MOLECULES IN FLUIDS AND LIQUID CRYSTALS

1990 ◽  
Vol 8 (5) ◽  
pp. 727-738 ◽  
Author(s):  
I. Dozov ◽  
S. Temkin ◽  
N. Kirov

1992 ◽  
Vol 47 (4) ◽  
pp. 625-626 ◽  
Author(s):  
V. I. Stepanov

AbstractThe calculation of the viscosity of liquid crystals based on the rotational diffusion approximation recently reported by Osipov and Terentjev [1 a] is critically examined. It is shown that the main result of their treatment - the evaluation of the activational exponent - arises from the neglect of the second derivative of the distribution function with respect to the azimuthal angle in the Fokker-Planck equation. The correct asymptotic formula for the rotational viscosity coefficient is derived.


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