ON THE FERROMAGNETIC PHASE TRANSITION IN NANO ZnO:Mn BY ELECTRON PARAMAGNETIC RESONANCE

2009 ◽  
Vol 23 (15) ◽  
pp. 3221-3229 ◽  
Author(s):  
P. VINOTHA BOORANA LAKSHMI ◽  
B. RANGANATHAN ◽  
N. RAJKUMAR ◽  
K. RAMACHANDRAN

Nanocrystalline samples of Zn 1-x Mn x O (x = 0.0, 0.01, 0.02, 0.1 and 0.2) were synthesized by solid state reaction and characterized by X-ray diffraction and electron paramagnetic resonance (EPR) at room temperature. EPR studies showed an evidence of ferromagnetism above room temperature.

Synthesis ◽  
2018 ◽  
Vol 50 (18) ◽  
pp. 3671-3678
Author(s):  
Didier Bourissou ◽  
Amos Rosenthal ◽  
Sonia Mallet-Ladeira ◽  
Ghenwa Bouhadir

Two new P-stabilized boryl radicals [Ph2P(naph)BAr] (Ar = Tip and Ter) have been prepared and characterized by electron paramagnetic resonance spectroscopy. These radicals are persistent for several days in solution at room temperature. The high steric congestion at boron does not prevent radical reactivity. Two different types of dimerization equilibrium have been observed. The structures of the dimers have been unambiguously established by X-ray diffraction crystallography.


2007 ◽  
Vol 555 ◽  
pp. 95-100
Author(s):  
D. Milivojević ◽  
Jovan Blanuša ◽  
V. Spasojević ◽  
V. Kusigerski ◽  
B. Babić-Stojić

Zn-Mn-O semiconductor crystallites with nominal manganese concentration x = 0.01, 0.02, 0.04 and 0.10 were synthesized by a solid state reaction route using oxalate precursors. Thermal treatment procedure was carried out in air at different temperatures in the range 400 - 900°C. The samples were investigated by X-ray diffraction, magnetization measurements and electron paramagnetic resonance. X-ray analysis reveals that dominant crystal phase in the Zn-Mn-O system corresponds to the wurtzite structure of ZnO. Room temperature ferromagnetism is observed in the Zn-Mn-O samples with lower manganese concentration, x ≤ 0.04, thermally treated at low temperature (500°C). Saturation magnetization in the sample with x = 0.01 is found to be 0.05 μB/Mn. The ferromagnetic phase seems to be developed by Zn diffusion into Mn-oxide grains.


2012 ◽  
Vol 217-219 ◽  
pp. 737-740
Author(s):  
Han Jie Huang

In this work, a visible light-induced LaVO4/TiO2 composite has been characterized by powder X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) and spin-trapping electron paramagnetic resonance (EPR) to reveal the structure and visible light photocatalytic mechanism for the decompostion of benzene in gas-phase. Based on the experimental results, a visible light-induced photochemical processes on LaVO4/TiO2 are proposed and elucidated.


2014 ◽  
Vol 02 (02) ◽  
pp. 114-120
Author(s):  
Tanguturi Ravindra Reddy ◽  
Krishnan Thyagarajan ◽  
Ovidio Almanza Montero ◽  
Sanapa Reddy Lakshmi Reddy ◽  
Tamio Endo

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