Unique molecular structure and properties of novel purple intermediates of phthalocyanine derivative
2003 ◽
Vol 07
(01)
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pp. 58-69
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Keyword(s):
X Ray
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When long alkylthio-substituted phthalocyaninato copper(II) complexes, ( C n S )8 PcCu , were rapidly prepared in an α-diol by using our developed see-through microwave reactor and/or a conventional hot stirrer, novel purple intermediates were selectively obtained instead of the expected green complex, ( C n S )8 PcCu , for some specific combinations of the reaction solvent and metal salt. The reaction conditions to obtain the purple intermediates were established and the unique molecular structure was clarified for a buthylthio-substituted intermediate by X-ray single crystal structure analysis.
2011 ◽
Vol 13
(4)
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pp. 684-690
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1998 ◽
Vol 52
◽
pp. 702-708
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1970 ◽
Vol 3
(2)
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pp. 97-98
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2005 ◽
Vol 60
(5)
◽
pp. 569-571
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1992 ◽
Vol 200
(3-4)
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1987 ◽
Vol 109
(2)
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pp. 592-594
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