In-Situ Measurement of Oxygen Partial Pressure in the Cathode Flow Field with a Hydrophilic Surface

2013 ◽  
Vol 58 (1) ◽  
pp. 1791-1797 ◽  
Author(s):  
S. Hirano ◽  
M. Potocki ◽  
G. Saloka ◽  
S. Palluconi ◽  
J. Crafton
2019 ◽  
Vol 33 (1) ◽  
pp. 1241-1249 ◽  
Author(s):  
William Epting ◽  
Katherine C. Hess ◽  
Shawn Litster

1991 ◽  
Vol 6 (10) ◽  
pp. 2054-2058 ◽  
Author(s):  
B-S. Hong ◽  
T.O. Mason

Via in situ electrical property measurements (conductivity, Seebeck coefficient) over the temperature range 500–800 °C and oxygen partial pressure range 10−4-1 atm, the equilibrium transport properties and stability range of YBa2Cu4O8 were determined. YBa2Cu4O8 behaves like the intrinsically mixed-valent compound, magnetite (Fe3O4), with small variations in electrical properties with changes in oxygen partial pressure. The decomposition boundary to YBa2Cu3O6+y (or YBa2Cu3.5O7.5±z) and CuO occurs at log(po2, atm) = −1.24 × 104/T(K) + 11.01(773 ⋚ T(K) ⋚ 1073).


2005 ◽  
Vol 20 (10) ◽  
pp. 2745-2753 ◽  
Author(s):  
Yung-Shou Ho ◽  
Fong-Shung Huang ◽  
Fu-Hsing Lu

In this research, the influences of the oxygen impurity contained in the commercially available nitrogen gas on the reactions of chromium pellets with nitrogen were investigated in the temperature range 600–1350 °C. A small amount of oxygen competed with the majority N2 to react with chromium in the annealing process. Analyzing the in situ oxygen partial pressure changes during annealing proved that the dissolution of oxygen in Cr and/or resultant CrxN (CrN or Cr2N) was exothermic and the solubility decreased with increasing temperature. It was found that the oxygen partial pressure decreased drastically to about 10−22 atm when specimens were annealed at 600 °C compared to a mere 10−5 atm for a blank test, while its value increased with temperature. The oxidation involved simultaneous dissolution of oxygen in specimens and formation of oxide scale. Moreover, comparing the aforementioned results with those obtained from additional annealing experiments preformed in argon gas showed that the formation of Cr2O3 might stem mainly from oxidation of the resultant nitrides instead of the metallic chromium.


1994 ◽  
Vol 33 (Part 2, No. 5B) ◽  
pp. L718-L721 ◽  
Author(s):  
Yong Ki Park ◽  
Keunseop Park ◽  
Soon-Gul Lee ◽  
Dong Chan Shin ◽  
Jong-Chul Park

2012 ◽  
Vol 152 (4) ◽  
pp. 278-283 ◽  
Author(s):  
Takanori Itoh ◽  
Saori Shirasaki ◽  
Hironori Ofuchi ◽  
Sayaka Hirayama ◽  
Tetsuo Honma ◽  
...  

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