Entropymetry of Lithium Intercalation in Spinel Manganese Oxide: Effect of Lithium Stoichiometry

2019 ◽  
Vol 1 (26) ◽  
pp. 87-96 ◽  
Author(s):  
Rachid Yazami ◽  
Yvan Reynier ◽  
Brent Fultz
2016 ◽  
Vol 212 ◽  
pp. 458-464 ◽  
Author(s):  
Riki Kataoka ◽  
Mitsunori Kitta ◽  
Hiroyuki Ozaki ◽  
Nobuhiko Takeichi ◽  
Tetsu Kiyobayashi

1996 ◽  
Vol 453 ◽  
Author(s):  
C. Julien ◽  
A. Rougier ◽  
G. A. Nazri

AbstractWe report synthesis, crystal structure, lattice dynamics, and electrochemical features of the lithiated manganese oxide spinel prepared through solid state reaction by careful selection of precursors and synthesis conditions. Elemental analysis shows that the material is a lithium-rich spinel phase. X-ray diffraction data and Rietveld refinement indicate formation of a single phase, impurity free, normal spinel of LiMn2O4. Lattice dynamics have been investigated by vibrational spectroscopy and group theoretical analysis has been carried out. Electrochemical performances of the lithiated spinel manganese oxide have been investigated, and the voltage profile of the cathode during lithium intercalation-deintercalation processes, close to equilibrium, has been obtained. The upper 4-volt plateau provides over 130 mA h/g with an excellent cyclability.


2006 ◽  
Vol 107 (1) ◽  
pp. 225-231 ◽  
Author(s):  
Liancai Ning ◽  
Jinping Wu ◽  
Chenggang Zhou ◽  
Shujuan Yao ◽  
Zhenbang Pi ◽  
...  

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