Fuel Cell Performance and Water Transport Properties of Asymmetric Bi-Layer Proton Conducting Membranes

Author(s):  
Luis Breziner ◽  
Peter Strahs ◽  
Parsaoran Hutapea

The objective of this research is to analyze the effects of vibration on the performance of hydrogen PEM fuel cells. It has been reported that if the liquid water transport across the gas diffusion layer (GDL) changes, so does the overall cell performance. Since many fuel cells operate under a vibrating environment –as in the case of automotive applications, this may influence the liquid water concentration across the GDL at different current densities, affecting the overall fuel cell performance. The problem was developed in two main steps. First, the basis for an analytical model was established using current models for water transport in porous media. Then, a series of experiments were carried, monitoring the performance of the fuel cell for different parameters of oscillation. For sinusoidal vibration at 10, 20 and 50Hz (2 g of magnitude), a decrease in the fuel cell performance by 2.2%, 1.1% and 1.3% was recorded when compared to operation at no vibration respectively. For 5 g of magnitude, the fuel cell reported a drop of 5.8% at 50 Hz, whereas at 20 Hz the performance increased by 1.3%. Although more extensive experimentation is needed to identify a relationship between magnitude and frequency of vibration affecting the performance of the fuel cell as well as a throughout examination of the liquid water formation in the cathode, this study shows that sinusoidal vibration, overall, affects the performance of PEM fuel cells.


2006 ◽  
Vol 11-12 ◽  
pp. 149-152
Author(s):  
Thanganathan Uma ◽  
Masayuki Nogami

Sol-gel derived high proton conducting P2O5-SiO2-PMA (phosphomolybdic acid, H3PMo12O40 nH2O) glasses as electrolyte were used for the H2/O2 fuel cell performance at 30 °C under humidification with H2- based gas at the anode and O2- based gas at the cathode. The performance of the electrode was evaluated by the measurement of cell potential-current density plots. While the polarization curve yields data related to basic cell performance, more detailed information can be found by electrochemical measurements with an impedance analyzer. The power density shows a similar pattern to current density. The maximum power density value of 16.2 mW/cm2 was achieved with 0.1 mg/cm2 of Pt/C loading electrode and P2O5-SiO2-PMA (4-92-4 mol %) at 30°C with 30 % humidity. The glass membrane here plays a key role as electrolyte medium for proton transport and barrier to avoid the direct contact between fuel and oxygen.


Author(s):  
Christoph Csoklich ◽  
Hong Xu ◽  
Federica Marone ◽  
Thomas J. Schmidt ◽  
Felix N. Büchi

2012 ◽  
Vol 37 (7) ◽  
pp. 6153-6160 ◽  
Author(s):  
Jingling Yan ◽  
Xiaoming Huang ◽  
Hunter D. Moore ◽  
Chao-Yang Wang ◽  
Michael A. Hickner

2016 ◽  
Vol 18 (18) ◽  
pp. 13066-13073 ◽  
Author(s):  
Hiroshi Iden ◽  
Atsushi Ohma ◽  
Tomomi Tokunaga ◽  
Kouji Yokoyama ◽  
Kazuhiko Shinohara

The optimization of the catalyst layers is necessary for obtaining a better fuel cell performance and reducing fuel cell cost.


2021 ◽  
pp. 50644
Author(s):  
Irina A. Stenina ◽  
Polina A. Yurova ◽  
Tatyana S. Titova ◽  
Marina A. Polovkova ◽  
Oleg V. Korchagin ◽  
...  

2010 ◽  
Vol 195 (1) ◽  
pp. 170-174 ◽  
Author(s):  
N. Gourdoupi ◽  
J.K. Kallitsis ◽  
S. Neophytides

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