(Invited) Tube Length Dependence of Far-Infrared Absorption of Single-Walled Carbon Nanotubes

Author(s):  
E. Kok ◽  
J. N. Tey ◽  
J. Wei

In our research, we aim to formulate SWNTs ink and develop a methodology to create enhanced conductive flexible transparent SWNTs films that have the potential to possibly reduce the use of ITO. In our preliminary findings, we achieved a sheet resistance of 25.1 kΩ/sq with ∼93% transparency (excluding film) by spraying a unsorted purified pristine SWNTs. In-house separated M-SWNTs, prepared using agarose gel separation methods, were sprayed with sheet resistance of 3.3 kΩ/sq and ∼86% transparent.. Investigation of tube length with respect to conductivity was also studied — nanotubes were sonicated for different durations (thus affecting tube length) before separation and spraying.


2013 ◽  
Vol 27 (16) ◽  
pp. 1350117 ◽  
Author(s):  
P. SAPNA ◽  
T. J. SINGH

Thermal conductivity of single-walled carbon nanotubes has been calculated considering the three-phonon and four-phonon processes. The contribution of the acoustic modes and optical modes in the relaxation rate of the phonon–phonon interaction and hence to the thermal conductivity have been considered. The thermal conductivity has been calculated for the (8, 0), (10, 0), (11, 0) and (13, 0) zigzag semiconducting nanotubes having different radii. It is found that the thermal conductivity increases linearly at low temperatures which is nearly T2 below 30 K and after reaching a peak, it decreases as aT-1 - bT-2 where a and b are constants and b > a at higher temperatures. It is also found that the thermal conductivity increases with increasing radius of the tube due to the independent effect of three-phonon process and four-phonon process. The thermal conductivity is also found to decrease with increasing tube length due to four-phonon process.


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