infrared absorption spectra
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2021 ◽  
Vol 88 (6) ◽  
pp. 933-941
Author(s):  
V. L. Vesnin

The article presents the results of studies of infrared absorption spectra of saturated vapors of alcohols and alcohol-containing mixtures in the range of 1.3—1.5 μm. A method was developed for the quantitative determination of the composition of water-alcohol mixtures based on the use of multiple linear regression, and a range of methanol concentrations was determined, in which the nonlinearity of the dependence of the concentration of alcohols in saturated vapors over a liquid mixture on the concentration of alcohols in this liquid mixture does not significantly affect the results of analysis of the mixture composition. A method for optimizing a set of wavelengths for multiple linear regression, based on minimizing the mean-square error in determining the concentration is proposed and implemented. The developed methods make it possible to determine the presence of small (<1%) amounts of methanol against the background of large amounts of ethanol and water using relatively inexpensive and accessible spectroscopic equipment.


Author(s):  
O. Cherkasova ◽  
M. Konnikova ◽  
T. Heinz ◽  
M. Nazarov ◽  
A. Kuryanova ◽  
...  

2021 ◽  
Vol 2 (68) ◽  
pp. 57-60
Author(s):  
M. Shamsutdinova ◽  
F. Dzhebirkhanova

The synthesis of complex compounds of 4 - [(2,4-dimethoxybenzyl) amino] benzoic acid (HL) with ions of samarium (III), europium (III), terbium (III), gadolinium (III) and dysprosium (III). According to the data of elemental analysis and thermogravimetry, the obtained complexes are hydrates of the composition LnL3 · nH2O, where n = 0-2. The area of their thermal stability is in the range from 100 ° С to 150 ° С. Electronic and infrared absorption spectra of the ligand and complexes with rare-earth metal ions have been measured. According to the IR spectra, the coordination of the ligand with the metal ion occurs at the carboxyl group. The carboxyl group is bidentate coordinated. To excite luminescence, a line of a mercury lamp with a wavelength of 248 nm was used. The highest luminescence intensity is observed for the coordination compounds Eu3 +, Tb3 +, Sm3 +, and Dy3 +.


Author(s):  
В.А. Рыжов ◽  
Б.Т. Мелех ◽  
Л.П. Казакова

Abstract Infrared absorption spectra of chalcogenide alloys of the GST system with the compositions Ge14Sb29Te57 and Ge15Sb15Te70 in the amorphous and crystalline state were measured and analyzed in the range of 20 – 400 cm– 1 (0.6 – 12 THz) at room temperature. Absorption at these frequencies is due to the manifestation of correlated torsional vibrations of structural units of the amorphous alloy and phonon modes of the crystal. The performed assignment of absorption bands and the revealed differences in the IR spectra make it possible to more confidently represent the possible molecular mechanism of reversible amorphous-crystalline transformations in the studied phase-changing materials


2021 ◽  
Vol 129 (8) ◽  
pp. 1068
Author(s):  
Д.В. Булыга ◽  
С.К. Евстропьев ◽  
Н.К. Кузьменко ◽  
Р.В. Садовничий ◽  
Н.В. Никоноров

Experimental results of polymer-salt synthesis of Yb:YAG nanopowders and analysis of their structure and luminescent properties are presented. Infrared absorption spectra of synthesized materials are presented. The results of XRD analysis show that Yb:YAG nanocrystals with sizes of 18-35 nm form at a temperature of 900-1100 °С. The study on photoluminescence spectra and decay curves shows that properties of synthesized powders are close to properties of macroscopic materials produced by traditional high-temperature methods.


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