Grain and Grain Boundary Conductivity in Nanocrystalline Yttria-Stabilized-Zirconia Thin Films

2012 ◽  
Vol 45 (1) ◽  
pp. 235-239 ◽  
Author(s):  
B. Scherrer ◽  
J. G. Grolig ◽  
M. Prestat ◽  
L. J. Gauckler

2005 ◽  
Vol 106 ◽  
pp. 83-86
Author(s):  
A. Rizea ◽  
Jean Marc Raulot ◽  
C. Petot ◽  
Georgette Petot-Ervas ◽  
Gianguido Baldinozzi

This work was directed at a comprehensive study of the role of the nanostructure and nanochemistry on the transport properties of yttria-stabilized zirconia. Alumina additions lead to a decrease of sgb when the samples have clean grain boundaries, while sgb goes through a maximum in samples having glassy grain boundaries. The differences were attributed to the strong interaction between Al2O3 and SiO2 impurities leading to a glassy phase depletion at the grain-boundaries, due to a change in wettability. Moreover, XPS analyses show that Si and Y segregate near these interfaces according to a kinetic demixing process, explaining why a faster cooling rate after sintering has a beneficial effect on sgb.


2012 ◽  
Vol 45 (1) ◽  
pp. 189-192 ◽  
Author(s):  
M. V. Schlupp ◽  
H. Ma ◽  
J. Martynczuk ◽  
M. Prestat ◽  
L. J. Gauckler

2010 ◽  
Vol 10 (11) ◽  
pp. 7411-7415 ◽  
Author(s):  
Victor Ivanov ◽  
Sergey Shkerin ◽  
Alexey Rempel ◽  
Vladimir Khrustov ◽  
Alexander Lipilin ◽  
...  

2016 ◽  
Vol 18 (15) ◽  
pp. 10486-10491 ◽  
Author(s):  
Edmund M. Mills ◽  
Matthias Kleine-Boymann ◽  
Juergen Janek ◽  
Hao Yang ◽  
Nigel D. Browning ◽  
...  

The grain boundary resistance of nano-columnar yttria-stabilized zirconia thin films is almost completely eliminated near the film–substrate interface through substrate induced magnesium doping.


2000 ◽  
Vol 147 (7) ◽  
pp. 2822 ◽  
Author(s):  
Jong-Heun Lee ◽  
Toshiyuki Mori ◽  
Ji-Guang Li ◽  
Takayasu Ikegami ◽  
Manabu Komatsu ◽  
...  

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