Electrochemical Reduction of Carbon Dioxide with Nitrogen-Doped Copper Nanoparticles

2021 ◽  
Vol 759 ◽  
pp. 143575
Author(s):  
Zhiyi Qin ◽  
Xiupeng Jiang ◽  
Yue Cao ◽  
Shanshan Dong ◽  
Feng Wang ◽  
...  

2013 ◽  
Vol 85 (22) ◽  
pp. 11159-11159 ◽  
Author(s):  
Nianjun Yang ◽  
Fang Gao ◽  
Christoph E. Nebel

2018 ◽  
Vol 8 (10) ◽  
pp. 1702524 ◽  
Author(s):  
Yong Zhao ◽  
Jiaojiao Liang ◽  
Caiyun Wang ◽  
Jianmin Ma ◽  
Gordon G. Wallace

Rare Metals ◽  
2021 ◽  
Author(s):  
Shuai Zhang ◽  
Xin-Tong Gao ◽  
Peng-Fei Hou ◽  
Tie-Rui Zhang ◽  
Peng Kang

2018 ◽  
Vol 22 (05) ◽  
pp. 406-412 ◽  
Author(s):  
Siyu Zhang ◽  
Xue Zhang ◽  
Huiyuan Liu ◽  
Yang Lv ◽  
Zhongjun Hou ◽  
...  

Copper nanoparticles frequently exhibit unique electrocatalytic activity for the electrochemical reduction of carbon dioxide. However, the synthesis of Cu nanoparticles in aqueous systems remains rare. Herein, we report the synthesis of copper nanoparticles by using a zinc(II) porphyrin-based photocatalytic method in the presence of polyacrylic acid sodium salt (PAA) in water under visible light irradiation, leading to a series of Cu nanoparticles with relatively small average sizes ranging from 69 to 97 nm. PAA molecules adsorbed on Cu nanoparticles were simply removed by washing with copious amount of water. The purified Cu nanoparticles show some activity toward the electrochemical reduction of carbon dioxide as evidenced by linear sweep voltammetry (LSV) and gas chromatography (GC).


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