The Localized Corrosion of Ni-Cr-Mo-W Alloy UNS N06022 in Aprotic Solvents Containing Chlorides

2021 ◽  
Vol MA2021-02 (9) ◽  
pp. 556-556
Author(s):  
Pedro Atz Dick ◽  
Robert G Kelly
Keyword(s):  
Localized Corrosion ◽  
Aprotic Solvents

TEM study of a biofilm on copper corrosion

1996 ◽  
Vol 54 ◽  
pp. 220-221
Author(s):  
W. A. Chiou ◽  
N. Kohyama ◽  
B. Little ◽  
P. Wagner ◽  
M. Meshii
Keyword(s):  
Marine Bacterium ◽  
Culture Medium ◽  
Copper Alloys ◽  
Pure Copper ◽  
Localized Corrosion ◽  
Natural Seawater ◽  
Copper Corrosion ◽  
New Approach ◽  
The Past ◽  
Copper Tolerant

The corrosion of copper and copper alloys in a marine environment is of great concern because of their widespread use in heat exchangers and steam condensers in which natural seawater is the coolant. It has become increasingly evident that microorganisms play an important role in the corrosion of a number of metals and alloys under a variety of environments. For the past 15 years the use of SEM has proven to be useful in studying biofilms and spatial relationships between bacteria and localized corrosion of metals. Little information, however, has been obtained using TEM capitalizing on its higher spacial resolution and the transmission observation of interfaces. The research presented herein is the first step of this new approach in studying the corrosion with biological influence in pure copper.Commercially produced copper (Cu, 99%) foils of approximately 120 μm thick exposed to a copper-tolerant marine bacterium, Oceanospirillum, and an abiotic culture medium were subsampled (1 cm × 1 cm) for this study along with unexposed control samples.

VLX 954

Alloy Digest ◽  
1995 ◽  
Vol 44 (4) ◽  
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
High Temperature ◽  
Austenitic Stainless Steel ◽  
Physical Properties ◽  
Tensile Properties ◽  
Sea Water ◽  
Heat Treating ◽  
Localized Corrosion ◽  
Temperature Performance

Abstract VLX 954 is an austenitic stainless steel with 6% (nominal) molybdenum. The alloy is particularly resistant to localized corrosion in sea water and chloride environments. This datasheet provides information on composition, physical properties, elasticity, and tensile properties. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: SS-589. Producer or source: DMV Stainless USA Inc.

ZERON 25

Alloy Digest ◽  
1995 ◽  
Vol 44 (3) ◽  
Keyword(s):  
Fracture Toughness ◽  
Corrosion Resistance ◽  
Hydrogen Sulfide ◽  
Mechanical Strength ◽  
Physical Properties ◽  
Tensile Properties ◽  
Heat Treating ◽  
Oil Field ◽  
Localized Corrosion ◽  
Oil Gas

Abstract ZERON 25 is an alloy developed to combat severe oil field duties where oil, gas, water are contaminated with high levels of chlorides and hydrogen sulfide. The alloy has good mechanical strength and resistance to localized corrosion. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as fracture toughness. It also includes information on corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: SS-584. Producer or source: Weir Material Services Ltd.

URANUS 76N

Alloy Digest ◽  
2009 ◽  
Vol 58 (1) ◽  
Keyword(s):  
Fracture Toughness ◽  
Corrosion Resistance ◽  
Shear Strength ◽  
Physical Properties ◽  
Tensile Properties ◽  
Heat Treating ◽  
Localized Corrosion ◽  
High Chromium ◽  
Equivalent Number ◽  
Nitrogen Contents

Abstract URANUS 76N contains high chromium, molybdenum, and nitrogen contents and has a pitting resistance equivalent number (PREN) ≥ 40. These factors explain why the duplex austenitic/ferritic stainless grade is very resistant to localized corrosion. The alloy has been used for offshore applications. This datasheet provides information on composition, physical properties, tensile properties, and shear strength as well as fracture toughness. It also includes information on corrosion resistance as well as forming, heat treating, and joining. Filing Code: SS-1028. Producer or source: Industeel USA, LLC.

Solvation of ions by dipolar aprotic solvents and water. A CNDO/2 study

1985 ◽  
Vol 50 (11) ◽  
pp. 2493-2508 ◽  
Author(s):  
Petr Kyselka ◽  
Zdeněk Havlas ◽  
Ivo Sláma
Keyword(s):  
Binary Mixtures ◽  
Quantum Chemical ◽  
Chemical Method ◽  
Molecular Structures ◽  
Dimethyl Sulphoxide ◽  
Ternary Mixtures ◽  
Aprotic Solvents ◽  
Quantum Chemical Method ◽  
Solvation Of Ions ◽  
Dipolar Aprotic Solvents

Solvation of Li+, Be2+, Na+, Mg2+, and Al3+ ions has been studied in binary mixtures with dimethyl sulphoxide, dimethylformamide, acetonitrile and water, and in ternary mixtures of the organic solvents with water. The CNDO/2 quantum chemical method was used to calculate the energies of solvation, molecular structures and charge distributions for the complexes acetonitrile...ion (1:1, 2:1, 4:1), dimethyl sulphoxide...ion (1:1), dimethylformamide...ion (1:1), and acetonitrile (dimethyl sulphoxide, dimethylformamide)...ion...water (1:1:1).

Oxidation of (1-hydroxybenzyl)ferrocene and its derivatives substituted in phenyl ring with bis(triphenylsilyl) chromate

1982 ◽  
Vol 47 (12) ◽  
pp. 3375-3380 ◽  
Author(s):  
Jaroslav Holeček ◽  
Karel Handlíř ◽  
Milan Nádvorník ◽  
Milan Vlček
Keyword(s):  
Linear Dependence ◽  
Rate Constants ◽  
Oxidation Rate ◽  
Phenyl Ring ◽  
Equilibrium Constants ◽  
Aprotic Solvents ◽  
Protonation Equilibrium ◽  
Oxidation Of Alcohols ◽  
Hammett Σ Constants ◽  
Sulphuric Acid Medium

Kinetics have been studied of oxidation of (1-hydroxybenzyl)ferrocenes substituted in phenyl ring with bis(triphenylsilyl) chromate in benzene solutions as well as protonation of these alcohols in sulphuric acid medium. Logarithms of the oxidation rate constants (kobs, 20-40 °C) and those of the protonation equilibrium constants (KR+, 25 °C) show linear dependence on the Hammett σ constants, the ρ constant values being -0.86 to -0.40 and -2.50, respectively. These negative values suggest that the both processes are influenced by the same effects and confirm the mechanism proposed earlier for oxidation of alcohols with ferrocenyl substituent by action of bis(triphenylsilyl) chromate in aprotic solvents.

1H and 13C NMR spectra of 2,2’-disubstitutedtrans-azobenzenes suitable for preparation of metallized azo dyes

1991 ◽  
Vol 56 (10) ◽  
pp. 2160-2168 ◽  
Author(s):  
Josef Jirman
Keyword(s):  
Nmr Spectra ◽  
Electron Pair ◽  
Phenyl Group ◽  
Aprotic Solvents ◽  
1H And 13C Nmr ◽  
Predominant Form ◽  
Rapid Equilibrium ◽  
Dipolar Aprotic Solvents ◽  
Free Electron Pair ◽  
C Nmr

The 1H and 13C NMR spectra have been measured of six trans-azobenzenes substituted at 2 and 2’ positions with substituents favourable for complex formation with a metal (OH, NH2, NHCOCH3, COOH). From the standpoint of NMR such substituted trans-azobenzenes are present in solution in a rapid equilibrium following from rotation around the bond between C-1 of phenyl group and N atom of azo linkage. The predominant form has the substituent in the syn-position with respect to the free electron pair of the nearer azo nitrogen atom. The equilibrium is affected by dipolar aprotic solvents (such as hexadeuteriodimethyl sulfoxide) by decreasing the presence of the predominant form by 1 to 11%.

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