Nuclear magnetic resonance study of lung water compartments in the rat

1997 ◽  
Vol 272 (4) ◽  
pp. L772-L778
Author(s):  
S. Shioya ◽  
M. Haida ◽  
M. Fukuzaki ◽  
D. Kurita ◽  
C. Tsuji ◽  
...  

Nuclear magnetic resonance transverse relaxation time (T2) was previously measured in studies of lung water. The T2 decay curves for peripheral lung tissue were found to be multiexponential with two T2 components: T2 fast (T2f) and T2 slow (T2s). This behavior was explained by the compartmentalization of water, in which the protons of water are restricted and do not undergo rapid exchange between the compartments. We investigated the origin of the water for these T2 components using excised rat lungs. The effect of magnetic field inhomogeneity due to air-tissue interfaces was examined by degassing some lungs. The contribution of intravascular water was examined by perfusing the lungs with oil or NaCl solutions. Degassing produced a greater increase in the T2f than the T2s component, indicating that the water in the alveolar walls exposed to air spaces contributed to the T2f. Perfusion with oil decreased the T2s, indicating that intravascular water contributed to the T2s component. The effects of intravascular osmotic pressure on the T2f and T2s components suggest that intracellular water is related to the T2f component.

Geophysics ◽  
2019 ◽  
Vol 84 (2) ◽  
pp. MR73-MR84 ◽  
Author(s):  
Fatemeh Razavirad ◽  
Myriam Schmutz ◽  
Andrew Binley

We have evaluated several published models using induced polarization (IP) and nuclear magnetic resonance (NMR) measurements for the estimation of permeability of hydrocarbon reservoir samples. IP and NMR measurements were made on 30 samples (clean sands and sandstones) from a Persian Gulf hydrocarbon reservoir. We assessed the applicability of a mechanistic IP-permeability model and an empirical IP-permeability model recently proposed. The mechanistic model results in a broader range of permeability estimates than those measured for sand samples, whereas the empirical model tends to overestimate the permeability of the samples that we tested. We also evaluated an NMR permeability prediction model that is based on porosity [Formula: see text] and the mean of the log transverse relaxation time ([Formula: see text]). This model provides reasonable permeability estimations for the clean sandstones that we tested but relies on calibrated parameters. We also examined an IP-NMR permeability model, which is based on the peak of the transverse relaxation time distribution, [Formula: see text] and the formation factor. This model consistently underestimates the permeability of the samples tested. We also evaluated a new model. This model estimates the permeability using the arithmetic mean of log transverse NMR relaxation time ([Formula: see text]) and diffusion coefficient of the pore fluid. Using this model, we improved estimates of permeability for sandstones and sand samples. This permeability model may offer a practical solution for geophysically derived estimates of permeability in the field, although testing on a larger database of clean granular materials is needed.


2019 ◽  
Vol 2 (2) ◽  

The quality of a reservoir can be described in details by the application of transverse relaxation time of nuclear magnetic resonance fractal dimension. The objective of this research is to calculate fractal dimension from the relationship among transverse relaxation time of nuclear magnetic resonance, maximum transverse relaxation time of nuclear magnetic resonance and wetting phase saturation and to confirm it by the fractal dimension derived from the relationship among capillary pressure and wetting phase saturation. In this research, porosity was measured on real collected sandstone samples and permeability was calculated theoretically from capillary pressure profile measured by mercury intrusion techniques. Two equations for calculating the fractal dimensions have been employed. The first one describes the functional relationship between wetting phase saturation, transverse relaxation time of nuclear magnetic resonance, maximum transverse relaxation time of nuclear magnetic resonance and fractal dimension. The second equation implies to the wetting phase saturation as a function of capillary pressure and the fractal dimension. Two procedures for obtaining the fractal dimension have been developed. The first procedure was done by plotting the logarithm of the ratio between transverse relaxation time of nuclear magnetic resonance and maximum transverse relaxation time of nuclear magnetic resonance versus logarithm wetting phase saturation. The slope of the first procedure = 3-Df (fractal dimension). The second procedure for obtaining the fractal dimension was completed by plotting logarithm of capillary pressure versus the logarithm of wetting phase saturation. The slope of the second procedure = Df -3. The results show similarities between transverse relaxation time of nuclear magnetic resonance and capillary pressure fractal dimension.


2018 ◽  
Vol 51 (2) ◽  
pp. 74-80 ◽  
Author(s):  
Rongsheng Lu ◽  
Penkun Lei ◽  
Xinlong Zhou ◽  
Yun Jiang ◽  
Xiaowen Jiang ◽  
...  

2015 ◽  
Vol 18 (03) ◽  
pp. 400-406 ◽  
Author(s):  
A.. Tinni ◽  
E.. Odusina ◽  
I.. Sulucarnain ◽  
C.. Sondergeld ◽  
C. S. Rai

Summary The application of nuclear-magnetic-resonance (NMR) methods to evaluate the fluid content in hydrocarbon reservoirs requires the understanding of the NMR response of the fluids present in the rock. The presence of multiple fluids such as liquid, gaseous, or adsorbed phases in nanometer-sized pores (associated with various minerals and organic matter) adds another degree of complexity to the interpretation of NMR data in shales. We present a laboratory study on the NMR responses of brine, oil, and methane in shales at 2 MHz. NMR transverse relaxation time (T2) distributions were acquired on core plugs from the Haynesville, Barnett, and Woodford shale formations. The NMR T2 distributions were acquired after brine (2.5% potassium chloride) and oil (dodecane) imbibition and saturation. After brine imbibition, we observed an increase in porosity at T2 ≤ 1 ms. However, after saturation at increasing pressures we observe a porosity increase at T2 ≈ 6–20 ms. Dodecane imbibition and saturation induced a porosity increase at T2 ≈ 10 ms. The measurements with methane were conducted on Haynesville core plugs at a methane pressure of 4,000 psi. The NMR T2 signal of methane in shales appears to be at approximately 10 ms. These results show that the NMR response of methane and oil is very similar in shales. Monitoring the saturation increase with NMR shows that brine can enter the entire pore spectrum, whereas oil and methane have access only to a fraction of the pore space.


1986 ◽  
Vol 64 (9) ◽  
pp. 1845-1849 ◽  
Author(s):  
Alfred Delville ◽  
Christian Detellier

D–(−)-Penicillamine interactions with Zn(II) have been studied in aqueous solutions as a function of pH, penicillamine concentration, and temperature, using Zn-67 nuclear magnetic resonance. Longitudinal and transverse relaxation rate measurements show the presence in solution of complexes in fast exchange with the aquated Zn(II) cation, and belonging to the extreme narrowing regime. Using equilibrium constant values from the literature, the relaxation behaviour was modelled. Characteristic Zn-67 line width values for the two complexes Zn(Pen) (v = (6200 ± 500) Hz) and [Zn(Pen H)]+ (v = (6000 ± 1000) Hz) were found. Equality of the two values is in agreement with zinc chelation by the sulfhydryl and the amino groups.


Sign in / Sign up

Export Citation Format

Share Document