Theoretical Study of Rotational Spectroscopy of Acetonitrile-d3in the Ground and Different Excited Vibrational States
Keyword(s):
The millimeter-wave rotational spectra of the ground and excited vibrational states v8= 1 and v8= 2 of the symmetric top molecule CD3CN have been analyzed again. Thel= ± 1 in v8=1,l= 0 andl= ± 2 series in v8= 2 states have been assigned respectively. The assignment and analysis of the measurements with a least – squares procedure have made it possible to obtain the rotational, quartic and sextic centrifugal distortion constants with more reliable and higher accuracy. Analysis of the v8= 2 state gave the following rotational parameters: Aζ = 62218.96 MHz and xll= 87527.70 MHz. Investigation in v8= 2 state indicates thatl-resonance is observed for this molecule aroundk=xℓℓ+(A−B)−2AζAζ−(A−B)≈4.
1983 ◽
Vol 38
(12)
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pp. 1309-1319
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1989 ◽
Vol 44
(6)
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pp. 538-550
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1971 ◽
Vol 26
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pp. 128-131
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1977 ◽
Vol 32
(7)
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pp. 761-764
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2019 ◽
pp. 147-148
2019 ◽
pp. 35-36
1990 ◽
Vol 45
(9-10)
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pp. 1165-1168
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