Comparative Study on the AC Brekadown Voltage of Palm Fatty Acid Ester Insulation Oils Mixed With Iron Oxide Nanoparticles

Author(s):  
Mohd Safwan Mohamad ◽  
Hidayat Zainuddin ◽  
Sharin Ab Ghani ◽  
Imran Sutan Chairul

Mineral oils are are derived from petroleum which is a non-renewable and non-sustainable source, and therefore there is a critical need to develop alternative insulation oils for use in transformers.  Ester oils offer a number of benefits over mineral oils such as good biodegradability, high cooling stability, good oxidation stability and excellent insulation performance. Nowadays, nanotechnology has become one of the most important research fields in both the academia and industry and it has been shown in previous studies that nanoscale materials are beneficial for transformers. In this regard, the objective of this study is to compare the AC breakdown voltage of palm fatty acid ester (PFAE) oils mixed with iron oxide (Fe<sub>3</sub>O<sub>4</sub>) nanoparticles. The PFAE-based nanofluids are prepared using two methods: (1) Method I (weight-based method whereby the concentration of the Fe<sub>3</sub>O<sub>4 </sub>nanoparticles is 0.01 g/l) and (2) Method II (volume-fraction method whereby the concentration of the Fe<sub>3</sub>O<sub>4 </sub>nanoparticles is 0.01, 0.02 and 0.03%). The AC breakdown voltage test is conducted on the PFAE-based nanofluids in accordance with the ASTM D1816 standard test method. Weibull statistical analysis is carried out to analyse the AC breakdown voltage of fresh PFAE oil and PFAE-based nanofluids. It is found that there is enhancement of the AC breakdown voltage for all PFAE-based nanofluids with the exception of with the exception of one sample prepared using Method II (0.01% Fe<sub>3</sub>O<sub>4 </sub>nanoparticles).

Author(s):  
Mohd Safwan Mohamad ◽  
Hidayat Zainuddin ◽  
Sharin Ab Ghani ◽  
Imran Sutan Chairul

Mineral oils are are derived from petroleum which is a non-renewable and non-sustainable source, and therefore there is a critical need to develop alternative insulation oils for use in transformers.  Ester oils offer a number of benefits over mineral oils such as good biodegradability, high cooling stability, good oxidation stability and excellent insulation performance. Nowadays, nanotechnology has become one of the most important research fields in both the academia and industry and it has been shown in previous studies that nanoscale materials are beneficial for transformers. In this regard, the objective of this study is to compare the AC breakdown voltage of palm fatty acid ester (PFAE) oils mixed with iron oxide (Fe<sub>3</sub>O<sub>4</sub>) nanoparticles. The PFAE-based nanofluids are prepared using two methods: (1) Method I (weight-based method whereby the concentration of the Fe<sub>3</sub>O<sub>4 </sub>nanoparticles is 0.01 g/l) and (2) Method II (volume-fraction method whereby the concentration of the Fe<sub>3</sub>O<sub>4 </sub>nanoparticles is 0.01, 0.02 and 0.03%). The AC breakdown voltage test is conducted on the PFAE-based nanofluids in accordance with the ASTM D1816 standard test method. Weibull statistical analysis is carried out to analyse the AC breakdown voltage of fresh PFAE oil and PFAE-based nanofluids. It is found that there is enhancement of the AC breakdown voltage for all PFAE-based nanofluids with the exception of with the exception of one sample prepared using Method II (0.01% Fe<sub>3</sub>O<sub>4 </sub>nanoparticles).


1963 ◽  
Vol 114 (3) ◽  
pp. 820-822 ◽  
Author(s):  
H. S. Olcott ◽  
A. Dolev

2000 ◽  
Vol 2 (3) ◽  
pp. 177-185 ◽  
Author(s):  
Hui Yang ◽  
Bei Jiang ◽  
Ai-Jun Hou ◽  
Zhong-Wen Lin ◽  
Han-Dong Sun

2012 ◽  
Vol 60 (6) ◽  
pp. 1437-1446 ◽  
Author(s):  
Pearse McCarron ◽  
Wade A. Rourke ◽  
William Hardstaff ◽  
Brandy Pooley ◽  
Michael A. Quilliam

2007 ◽  
Vol 92 (11) ◽  
pp. 4327-4331 ◽  
Author(s):  
Maija Badeau ◽  
Veera Vihma ◽  
Tomi S. Mikkola ◽  
Aila Tiitinen ◽  
Matti J. Tikkanen

Abstract Context: The 17β-estradiol fatty acid esters are hormone derivatives with long-lasting estrogenic effect. They are transported in serum lipoproteins and thought to be sequestered in adipose tissue. Objective: Our objective was to determine the 17β-estradiol fatty acid ester concentrations in serum and adipose tissue in women of various hormonal states. Design: After several chromatographic steps separating esterified from free estradiol, time-resolved fluoroimmunoassay was used as a quantifying tool. Participants: Samples were obtained from pregnant women undergoing cesarean section (n = 13), or premenopausal (n = 8) and postmenopausal women (n = 6) during gynecological surgery. Main Outcome Measures: 17β-Estradiol and 17β-estradiol fatty acid ester concentrations in serum, and visceral and sc adipose tissue were examined. Results: The ratio of esterified to free estradiol in plasma increased with decreasing estradiol level from 0.5% in pregnant, to 15% in premenopausal and 110% in postmenopausal women. Estradiol esters constituted about 10% of the free estradiol present in adipose tissue in pregnancy. In nonpregnant women, most of the adipose tissue estradiol was in esterified form, the median ester to free ratio being elevated to 150–490%. After menopause, the overwhelming majority of estradiol in both free and esterified form was present in adipose tissue. Conclusions: The overall higher ester to free estradiol ratio in adipose tissue than in serum indicates active esterification capacity in adipose tissue. The predominance of esterified and free estradiol in postmenopausal adipose tissue compared with serum suggests in situ production and storage. Whether the estradiol esters have an independent physiological role in adipose tissue remains to be clarified.


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