Self-Assemblies of Cationic Porphyrins with Functionalized Water-Soluble Single-Walled Carbon Nanotubes

2009 ◽  
Vol 9 (10) ◽  
pp. 5795-5802 ◽  
Author(s):  
Pavel Kubát ◽  
Kamil Lang ◽  
Pavel Janda ◽  
Ota Frank ◽  
Irena Matulková ◽  
...  
2009 ◽  
Vol 255 (15) ◽  
pp. 7095-7099 ◽  
Author(s):  
Li Zhang ◽  
Qing-Qing Ni ◽  
Yaqin Fu ◽  
Toshiaki Natsuki

2006 ◽  
Vol 18 (25) ◽  
pp. 5864-5868 ◽  
Author(s):  
Jayanta Chattopadhyay ◽  
Felipe de Jesus Cortez ◽  
Soma Chakraborty ◽  
Nigel K. H. Slater ◽  
W. E. Billups

2008 ◽  
Vol 8 (3) ◽  
pp. 1545-1550 ◽  
Author(s):  
Liling Zeng ◽  
Nancy Pattyn ◽  
Andrew R. Barron

Single-walled carbon nanotubes (SWNTs) were functionalized by direct fluorination and subsequent reaction with 6-aminohexanoic acid for water-soluble carboxylic acid functionalized SWNTs (AHA-SWNTs). Both of the compounds were used as precursors to attach SWNTs to APTES coated silicon surfaces. AHA-SWNTs in aqueous solution were reacted with APTES self-assembled monolayers (SAMs) with coupling reagents N-(3-dimethylaminopropyl)-N′-ethylcarbodiimide (EDC) and N-hydroxysuccinimide (NHS). The surface coverage is a function of concentration of AHA-SWNTs, solvent and coupling method. While for the fluorinated SWNTs (F-SWNTs), direct addition of F-SWNTs to preformed APTES SAMs at 90 °C shows essentially no reaction, in contrast to the one-pot reaction of F-SWNTs with APTES molecules in the presence of SWNTs on a silicon substrate. This reaction route provides a convenient method to attach SWNTs to silicon surfaces.


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