scholarly journals Measurements of the vapor pressure of supercooled water using infrared spectroscopy

2008 ◽  
pp. 100731080323068
Author(s):  
Will Cantrell ◽  
Eli Ochshorn ◽  
Alexander Kostinski ◽  
Keith Bozin
Keyword(s):  
Infrared Spectroscopy ◽  
Vapor Pressure ◽  
Supercooled Water

scholarly journals Measurements of the Vapor Pressure of Supercooled Water Using Infrared Spectroscopy

2008 ◽  
Vol 25 (9) ◽  
pp. 1724-1729 ◽  
Author(s):  
Will Cantrell ◽  
Eli Ochshorn ◽  
Alexander Kostinski ◽  
Keith Bozin
Keyword(s):  
Infrared Spectroscopy ◽  
Vapor Pressure ◽  
Liquid Water ◽  
Water Film ◽  
Supercooled Water ◽  
Supercooled Liquid ◽  
Quantitative Change ◽  
Wetting Transition ◽  
Higher Temperature

Abstract Measurements are presented of the vapor pressure of supercooled water utilizing infrared spectroscopy, which enables unambiguous verification that the authors’ data correspond to the vapor pressure of liquid water, not a mixture of liquid water and ice. Values of the vapor pressure are in agreement with previous work. Below −13°C, the water film that is monitored to determine coexistence of liquid water (at one temperature) and ice (at another, higher, temperature) de-wets from the hydrophilic silicon prism employed in the authors’ apparatus. The de-wetting transition indicates a quantitative change in the structure of the supercooled liquid.

scholarly journals Temperature dependence of the vapor pressure and evaporation coefficient of supercooled water

2014 ◽  
Vol 119 (18) ◽  
pp. 10,931-10,940 ◽  
Author(s):  
James F. Davies ◽  
Rachael E. H. Miles ◽  
Allen E. Haddrell ◽  
Jonathan P. Reid
Keyword(s):  
Vapor Pressure ◽  
Temperature Dependence ◽  
Supercooled Water ◽  
Evaporation Coefficient

scholarly journals Accurate vapor pressure measurements of supercooled water in the temperature range between 252 K and 273 K

2020 ◽  
Vol 141 ◽  
pp. 105944
Author(s):  
G. Beltramino ◽  
L. Rosso ◽  
R. Cuccaro ◽  
S. Tabandeh ◽  
D. Smorgon ◽  
...  
Keyword(s):  
Vapor Pressure ◽  
Supercooled Water ◽  
Pressure Measurements ◽  
Temperature Range ◽  
Vapor Pressure Measurements

Crossover Equation and the Vapor Pressure of Supercooled Water

2009 ◽  
Vol 31 (4-5) ◽  
pp. 756-765 ◽  
Author(s):  
Jana Kalova ◽  
Radim Mares
Keyword(s):  
Vapor Pressure ◽  
Supercooled Water

Benzylamine Tartrate as an Organic Glass Substrate for Carbon Films by Evaporation

1970 ◽  
Vol 28 ◽  
pp. 484-485
Author(s):  
A. C. Faberge
Keyword(s):  
Vapor Pressure ◽  
Viscous Liquid ◽  
Glass Substrate ◽  
Room Temperature ◽  
Carbon Film ◽  
Carbon Films ◽  
Organic Glass ◽  
Spectroscopic Examination ◽  
Polymeric Substrates

Benzylamine tartrate (m.p. 63°C) seems to be a better and more convenient substrate for making carbon films than any of those previously proposed. Using it in the manner described, it is easy consistently to make batches of specimen grids as open as 200 mesh with no broken squares, and without individual handling of the grids. Benzylamine tartrate (hereafter called B.T.) is a viscous liquid when molten, which sets to a glass. Unlike polymeric substrates it does not swell before dissolving; such swelling of the substrate seems to be a principal cause of breakage of carbon film. Mass spectroscopic examination indicates a vapor pressure less than 10−9 Torr at room temperature.

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