A predictive artificial neural network model as a simulator of the extra virgin olive oil elaboration process

2017 ◽  
Vol 25 (4) ◽  
pp. 278-285 ◽  
Author(s):  
Estrella Funes ◽  
Yosra Allouche ◽  
Gabriel Beltrán ◽  
M Paz Aguliera ◽  
Antonio Jiménez

Nine neural models were created to predict the characteristics of the extra virgin olive oil developed as a quality objective and by-products. These models are designed with the help of data of process variables from physical sensors such as temperature, flows, current intensity, etc. and physicochemical ones like the near infrared spectrum of the olive mass. The results obtained for the extractability of the process (fatty content and moisture) were highly significant correlations (r2≥0.90) and with similar prediction errors (root mean of squared error of prediction) relative to other analysis techniques which measure the by-product directly. For prediction the models gave correlations above 0.94, with the exception of ultraviolet absorption coefficients (0.72–0.84), with small prediction errors and the quality indicator relative error range with values above the optimal 10. The set of developed artificial neural networks models constitute the basis of the global ‘simulator’ tool of the extra virgin olive oil process. This simulator can perform a predictive optimization of the process to pre-adjust the process variables according to the goals marked in productivity or quality, from an near infrared spectral database or by real-time scanning. This simulator could be integrated into a control system that performs the function of a ‘virtual plant’ that allows the said system to adjust in real time the appropriate variables to meet the objectives.

2010 ◽  
Author(s):  
A. G. Mignani ◽  
L. Ciaccheri ◽  
H. Ottevaere ◽  
H. Thienpont ◽  
L. Conte ◽  
...  

Lipids ◽  
2015 ◽  
Vol 50 (7) ◽  
pp. 705-718 ◽  
Author(s):  
Hormoz Azizian ◽  
Magdi M. Mossoba ◽  
Ali Reza Fardin-Kia ◽  
Pierluigi Delmonte ◽  
Sanjeewa R. Karunathilaka ◽  
...  

2020 ◽  
pp. 000370282097470
Author(s):  
Joshua M. Ottaway ◽  
J. Chance Carter ◽  
Kristl L Adams ◽  
Joseph Camancho ◽  
Barry Lavine ◽  
...  

The peroxide value (PV) of edible oils is a measure of the degree of oxidation, which directly relates to the freshness of the oil sample. Several studies previously reported in the literature have paired various spectroscopic techniques with multivariate analyses to rapidly determine PVs using field portable and process instrumentation; those efforts presented ‘best-case’ scenarios with oils from narrowly defined training and test sets. The purpose of this paper is to evaluate the use of near- and mid-infrared absorption and Raman scattering spectroscopies on oil samples from different oil classes, including seasonal and vendor variations, to determine which measurement technique, or combination thereof, is best for predicting PVs. Following PV assays of each oil class using an established titration-based method, global and global-subset calibration models were constructed from spectroscopic data collected on the 19 oil classes used in this study. Spectra from each optical technique were used to create partial least squares regression (PLSR) calibration models to predict the PV of unknown oil samples. A global PV model based on near-infrared (8 mm optical path length – OPL) oil measurements produced the lowest RMSEP (4.9), followed by 24 mm OPL near infrared (5.1), Raman (6.9) and 50 μm OPL mid-infrared (7.3). However, it was determined that the Raman RMSEP resulted from chance correlations. Global PV models based on low-level fusion of the NIR (8 and 24 mm OPL) data and all infrared data produced the same RMSEP of 5.1. Global subset models, based on any of the spectroscopies and olive oil training sets from any class (pure, extra light, extra virgin), all failed to extrapolate to the non-olive oils. However, the near-infrared global subset model built on extra virgin olive oil could extrapolate to test samples from other olive oil classes.


2015 ◽  
Vol 179 ◽  
pp. 35-43 ◽  
Author(s):  
Simone Faria Silva ◽  
Carlos Alberto Rodrigues Anjos ◽  
Rodrigo Nunes Cavalcanti ◽  
Renata Maria dos Santos Celeghini

2020 ◽  
Vol 159 ◽  
pp. 105544
Author(s):  
Flavia T. Borghi ◽  
Priscilla C. Santos ◽  
Francine D. Santos ◽  
Márcia H.C. Nascimento ◽  
Thayná Corrêa ◽  
...  

2015 ◽  
Author(s):  
Irina Torres Rodríguez ◽  
Maria-Teresa Sánchez ◽  
Maria-José de la Haba ◽  
DOLORES CATALINA PÉREZ MARÍN ◽  
JOSÉ EMILIO GUERRERO GINEL ◽  
...  

Author(s):  
Yannick Weesepoel ◽  
Martin Alewijn ◽  
Michiel Wijtten ◽  
Judith Müller-Maatsch

Abstract Background Current developments in portable photonic devices for fast authentication of extra virgin olive oil (EVOO) or EVOO with non-EVOO additions steer towards hyphenation of different optic technologies. The multiple spectra or so-called “fingerprints” of samples are then analyzed with multivariate statistics. For EVOO authentication, one-class classification (OCC) to identify “out-of-class” EVOO samples in combination with data-fusion is applicable. Objective Prospecting the application of a prototype photonic device (“PhasmaFood”) which hyphenates visible, fluorescence, and near-infrared spectroscopy in combination with OCC modelling to classify EVOOs and discriminate them from other edible oils and adulterated EVOOs. Method EVOOs were adulterated by mixing in 10–50% (v/v) of refined and virgin olive oils, olive-pomace olive oils, and other common edible oils. Samples were analyzed by the hyphenated sensor. OCC, data-fusion, and decision thresholds were applied and optimized for two different scenarios. Results: By high-level data-fusion of the classification results from the three spectral databases and several multivariate model vectors, a 100% correct classification of all pure edible oils using OCC in the first scenario was found. Reducing samples being falsely classified as EVOOs in a second scenario, 97% of EVOOs adulterated with non-EVOO olive oils were correctly identified and ones with other edible oils correctly classified at score of 91%. Conclusions Photonic sensor hyphenation in combination with high-level data fusion, OCC, and tuned decision thresholds delivers significantly better screening results for EVOO compared to individual sensor results. Highlights Hyphenated photonics and its data handling solutions applied to extra virgin olive oil authenticity testing was found to be promising.


NIR news ◽  
2017 ◽  
Vol 28 (4) ◽  
pp. 6-9 ◽  
Author(s):  
John KG Kramer ◽  
Hormoz Azizian

Fourier transform near infrared spectroscopy was recently demonstrated to be an excellent method to evaluate the authenticity and adulteration of extra virgin olive oil. Since this method is matrix dependent, it takes a chemical fingerprint of all the components which sets it apart from the targeted methods. Careful examinations of the Fourier transform near infrared spectra lead to the identification of a minor carbonyl overtone absorption at 5269 cm−1 associated with the volatile fraction in extra virgin olive oil that appears to be a reliable indicator of authenticity. The same spectra were used to identify the fatty acids present in the oil using models based on comparison to accurate GC data. Gravimetric mixtures of extra virgin olive oil with refined edible oils were then prepared to develop PLS1 calibration models to identify possible adulterants and by how much. The great varietal difference in olive oils made it necessary to develop four unique sets of PLS1 calibration models for each extra virgin olive oil variety. As a result, an extra virgin olive oil acceptance specification was established.


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