The role of metal-support interaction on the oxidation of noble metals supported on cerium based oxides

Catalysts ◽  
2018 ◽  
Vol 8 (7) ◽  
pp. 285 ◽  
Author(s):  
M. Grabchenko ◽  
N. Mikheeva ◽  
G. Mamontov ◽  
M. Salaev ◽  
L. Liotta ◽  
...  

Nowadays catalytic technologies are widely used to purify indoor and outdoor air from harmful compounds. Recently, Ag–CeO2 composites have found various applications in catalysis due to distinctive physical-chemical properties and relatively low costs as compared to those based on other noble metals. Currently, metal–support interaction is considered the key factor that determines high catalytic performance of silver–ceria composites. Despite thorough investigations, several questions remain debating. Among such issues, there are (1) morphology and size effects of both Ag and CeO2 particles, including their defective structure, (2) chemical and charge state of silver, (3) charge transfer between silver and ceria, (4) role of oxygen vacancies, (5) reducibility of support and the catalyst on the basis thereof. In this review, we consider recent advances and trends on the role of silver–ceria interactions in catalytic performance of Ag/CeO2 composites in low-temperature CO oxidation, soot oxidation, and volatile organic compounds (VOCs) abatement. Promising photo- and electrocatalytic applications of Ag/CeO2 composites are also discussed.


2016 ◽  
Vol 344 ◽  
pp. 90-99 ◽  
Author(s):  
E.V. Golubina ◽  
E.S. Lokteva ◽  
A.V. Erokhin ◽  
A.A. Veligzhanin ◽  
Ya.V. Zubavichus ◽  
...  

2017 ◽  
Vol 19 (6) ◽  
pp. 4199-4207 ◽  
Author(s):  
Catherine K. S. Choong ◽  
Luwei Chen ◽  
Yonghua Du ◽  
Martin Schreyer ◽  
S. W. Daniel Ong ◽  
...  

Effect of metal–support interaction on the generation of Rh–FexOy active sites is investigated via various in situ techniques.


2014 ◽  
Vol 488 ◽  
pp. 138-147 ◽  
Author(s):  
Vesna Havran Mueller ◽  
Milorad P. Duduković ◽  
Cynthia S. Lo

RSC Advances ◽  
2021 ◽  
Vol 11 (29) ◽  
pp. 17648-17657
Author(s):  
Ye Hwan Lee ◽  
Jeong Yoon Ahn ◽  
Dinh Duc Nguyen ◽  
Soon Woong Chang ◽  
Sung Su Kim ◽  
...  

The effect of metal–support interaction and role of support on catalytic performances during Ni based CO2 methanation reaction were investigated.


1994 ◽  
Vol 98 (40) ◽  
pp. 10180-10188 ◽  
Author(s):  
Bernard Coq ◽  
Pramod S. Kumbhar ◽  
Claude Moreau ◽  
Patrice Moreau ◽  
Francois Figueras

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